Page 23 - Introduction to Transfer Phenomena in PEM Fuel Cells
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12     Introduction to Transfer Phenomena in PEM Fuel Cells
                           1.1.4.2. Disadvantages
                             There are also six disadvantages:
                             – not present in the natural state;
                             – its lightness implies that its energy density is less favorable for storage
                                                                                          3
                           and transport in gaseous  form compared to natural gas (10.8 MJ/m  vs.
                                    3
                           39.8 MJ/m  for methane);
                             – flammability and detonation limit  with air wider than for natural gas
                           (4.1% – 72.5 vol. % and 5.1% – 13.5 vol. % for methane);
                             – minimum energy to be supplied to ignite it (10 times lower than that of
                           conventional hydrocarbons);

                             – flame almost invisible;
                             – low public support.


                           1.2. Types of fuel cell

                             The development of the hydrogen industry is largely based on fuel cell
                           technology. Its principle is not new, since it was discovered in 1839 by
                           William R. Grove, who invented the first fuel cell. At the time, this English
                           lawyer, an amateur researcher in  electrochemistry, found that by
                           recombining hydrogen and oxygen, it  is possible to simultaneously create
                           water, heat and electricity, and this is how the fuel cell was born.

                             In 1953, the engineer Francis T.  Bacon realized the first industrial
                           prototype of notable power (approximately 6 kW) [NGU 10]. Only NASA
                           exploited this technology in the 1960s to provide electricity to some of its
                           vessels such as Gemini and Apollo. Although the principle of the fuel cell
                           seems simple, its implementation is complex and expensive, which hitherto
                           prohibited its dissemination to the general public. Today, progress has been
                           made and the potential applications are numerous, from the supercondensile
                           fuel cell that produces only a few watts needed to power a mobile phone, to
                           the battery capable of producing 1 MW to provide electricity to a building.
                           The battery  can also be used for embedded applications in the transport
                           sector; there is now a whole range of fuel cells. The operating principle is
                           always the same, but different technologies are in development [CEA 18].
                           Fuel cells  will be one of the essential elements of the future hydrogen
                           economy; they have the capacity to meet all our energy needs while offering
                           high efficiency and very low-pollution technology.
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