Page 181 - Materials Chemistry, Second Edition
P. 181

166   LIFE CYCLE ASSESSMENT   HANDBOOK

              simple  sugars  or biomass. The plants, together  with  photosynthesis,  perform
              respiration  which  consists  of burning  organic matter  formed  by  photosynthe-
              sis, with  the  emission  of  carbon  dioxide  to  the  atmosphere.  In  addition,  the
              plants drop  to the ground  some  of  its remains, like the leaves, which  decom-
              pose in the soil and undergo  oxidation with formation  of carbon dioxide back
              into  the  atmosphere.  The  process  of  decomposition  of  organic  matter  in  soil
              can  also  lead  to  the  formation  of  complex  organic  substances,  called  humus,
              which  have an important  function  to absorb water  and  hold  it in the  ground.
              The plants  are the  source  of nutrients  for  all other  living organisms  and  thus
              feed  the food  chain, from  which the carbon returns to the atmosphere  through
              breathing, excrement and  decay  of dead  animals. In this paragraph we  briefly
              consider  the carbon  cycle as  a reminder  that  it is composed  of carbon  seques-
              tration  and  emissions, both  of  these  elements  need  to be  taken  together  into
              account  and  inserted  within  the  system boundaries  if  a  correct  calculation  of
              biogenic carbon balance is to be  performed.
                 For  a  long  time  food  LCA  studies  have  considered  the  carbon  balance  as
              net  zero, therefore,  data  about  carbon  sequestration  and  emissions  along  the
              life  cycle  of  the  product  were  not  included  in  the  boundaries  of  the  study.
              Following  this approach,  however,  some  positive and  negative  factors  of  cer-
              tain  agricultural  practices  have  not  been  properly  considered.  For  example,
              organic farming  or composting increases the soil organic matter, with  positive
              consequences  on biodiversity, but this has not been taken into account and  no
              effect  on the impact  categories, such  as global warming, was  considered.  The
              same  considerations  apply  to the practices  of  intensive  tillage operation  that,
              on  the  contrary,  deplete  the  soil  of  organic  substances.  Many  studies,  there-
              fore, currently focus on the verification  of the carbon balance, which is no lon-
              ger  zero, but  can be  modified  depending  on  which  effect  overrides  the  other
              (sequestration  or  emission).  Of  course,  the  effect  of  sequestration  prevails  in
              the  majority  of  studies  that  follow  this  approach;  therefore,  the  total  carbon
              balance is negative  (good  for the  environment).
                 In our  view,  if the carbon balance  refers  to the  effects  described  it is  impor-
              tant  not  to  report  the  carbon  gain  to  only  the  annual  cycle  of  the  crop but  it
              is necessary  to consider  the land  use  for  100 years, in line with  the  character-
              ization  factor  of  global  warming.  This  is because  many  of  the  practices,  that
              have  a  positive  effect  on  carbon  sequestration,  have  an  incremental  effect  in
              carbon sequestration  which  is not infinite  or continuous  in time. For example,
              the transition  from  conventional farming  to organic farming  in the early  years
              increases the organic matter  content  in the soil; however,  this value settles  for
              all subsequent  years and  does not  increase further.  The LCA should  therefore
              consider  the amount  of carbon  sequestered  through  agricultural  practice  and
              divide  it by  100 years,  so  that  the  environmental  gain  is not  assigned  just  to
              one year  of  observation.  The calculation  of  the  increase  in the amount  of  dry
              biomass stably incorporated  into the plant should  follow the same  approach.
                 Moreover, many studies stop at the farm  gate; the agricultural stage is  often
              partially  assessed,  without  accounting  for  the  emissions  which  occur  during
              the  use  of  fertilizers  and  pesticides  and  the  consumer-use  phase  is  often
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