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|68      Chapter 6  Nonferrous Metals and Alloys: Production, General Properties, and Applications

                         W yy*      into molten metal and tapping the froth that forms at the surface; this froth then
                                    solidifies into a foam. Other approaches to producing metal foam include (a) chem-
                                    ical vapor deposition (Section 34.6.2) onto a carbon foam lattice, (b) depositing
                                    metal powders from a slurry onto a polymer foam lattice, followed by sintering
                                    (Section 17.4) to fuse the metals and burn off the polymer, (c) doping molten or
                                    powder metals (Chapter 17) with titanium hydride (TiH2), which then releases
                                    hydrogen gas at the elevated casting or sintering temperatures, and (d) pouring
                                    molten metal into a porous salt and, upon cooling, leaching out the salt with acid.
                                         Metal foams have unique combinations of strength-to-density and stiffness-to-
                                    density ratios, although these ratios are not as high as the base metals themselves.
                                    However, metal foams are very lightweight and thus are attractive materials for aero-
                                    space applications. Because of their porosity, other applications of metal foams are
                                    filters and orthopedic implants. Recent developments include nicl<el-manganese-
                                    gallium metal foams with shape-memory characteristics (Section 6.13).
           FIGURE 6.3 Microstructure
           of a metal foam used in ortho-
           pedic implants to encourage
           bone ingrowth. Source: Cour- SUMMARY
           tesy of Zimmer, Inc.
                                    ° Nonferrous metals and alloys include a very broad range of materials. The most
                                      common are aluminum, magnesium, and copper and their alloys, which have a
                                      wide range of applications. For higher temperature service, nonferrous metals in-
                                      clude nickel, titanium, refractory alloys (molybdenum, niobium, tungsten, tanta-
                                      lum), and superalloys. Other nonferrous metal categories include low-melting
                                      alloys (lead, zinc, tin) and precious metals (gold, silver, platinum).
                                    ° Nonferrous alloys have a wide variety of desirable properties, such as strength,
                                      toughness, hardness, and ductility; resistance to high temperature, creep, and
                                      oxidation; a wide range of physical, thermal, and chemical properties; and high
                                      strength-to-weight and stiffness-to-weight ratios (particularly for aluminum
                                      and titanium). Nonferrous alloys can be heat treated to impart certain desired
                                      properties.
                                    ° Shape-memory alloys (smart materials) have unique properties, with numerous
                                      applications in a variety of products and manufacturing operations.
                                    ° Amorphous alloys (metallic glasses) have several properties that are superior to
                                      other materials, available in various forms, they have numerous applications.
                                    ° Metal foams are very lightweight and thus are attractive for aerospace as well as
                                      various other applications.
                                    ° As with all materials, the selection of a nonferrous material for a particular appli-
                                      cation requires a careful consideration of many factors, including design and
                                      service requirements, long-term effects, chemical affinity to other materials, envi-
                                      ronmental attack, and cost.



           KEY TERMS


           Amorphous alloys         Low-melting alloys       Precious metals          Smelting
           Babbitts                 Metal foam               Pyrometallurgy           Superalloys
           Brass                    Metallic glasses         Refractory metals        Temper designation
           Bronze                   Nonferrous               Shape-memory alloys
           Galvanizing              Pewter                   Smart materials
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