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Section 8.4  Glasses  205



               EXAMPLE 8.3 Ceramic Ball and Roller Bearings
               Silicon-nitride ceramic ball and roller bearings are  They have high wear resistance,  high fracture
               used when high temperature, high speed, or margin-  toughness, perform well with little or no lubrication,
               ally lubricated conditions occur. The bearings can be  and have low density. The balls have a coefficient of
               made entirely from ceramics, or just the ball and  thermal expansion one-fourth that of steel, and they
               rollers are ceramic and the races are metal, in which  can withstand temperatures  of up to 1400°C.
               case they are referred to as hybrid bearings (Fig. 8.2).  Produced from titanium and carbon nitride by
               Examples of machines utilizing ceramic and hybrid  powder-metallurgy  techniques,  the  full-density
               bearings include high-performance machine tool   titanium carbonitride (TiCN)  or silicon nitride
               spindles, metal-can seaming heads, high-speed flow  (Si3N4) bearing-grade material can be twice as hard
               meters, and the Space Shuttle’s main booster rocl<et’s  as chromium steel and 40% lighter. Components up
               liquid oxygen and hydrogen pumps.                to 300 mm in diameter can be produced.
                   The ceramic spheres have a diameter tolerance
               of 0.13 ,um and a surface roughness of 0.02 pm.










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                    FIGURE 8.2  A selection of ceramic bearings and races. Source: Courtesy of The Timken Company.




             Bioceramics.  Because of their strength and inertness, ceramics are used as bioma-
             terials (bioceramics) to replace joints in the human body, as prosthetic devices, and
             in dental work. Commonly used bioceramics are aluminum oxide, hydroxyapatite,
             tricalcium phosphate, silicon nitride, and various compounds of silica. Ceramic im-
             plants can be made porous, so that bone can grow into the porous structure (like-
             wise with porous titanium implants) and develop a strong bond with structural
             integrity.



             8.4    Glasses

             Glass is an amorphous solid with the structure of a liquid. It has been supercooled
             (cooled at a rate too high to allow crystals to form). Technically, glass is defined as
             an inorganic product of fusion that has cooled to a rigid condition without crystal-
             lizing. Glass has no distinct melting or freezing point; thus, its behavior is similar to
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