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220       Chapter 9  Composite Materials: Structure, General Properties, and Applications

                                   TABLE 9.2
                                     Typical Properties of Reinforcing Fibers
                                                     Tensile strength  Elastic modulus  Density
                                    Type                 (MPa)            (GPa)        (kg/m3 )  Relative cost
                                    Boron                3500                           2600       Highest
                                    Carbon
                                     High strength       3000                           1900       Low
                                     High modulus        2000                           1900       Low
                                    Glass
                                     E-type               3500                          2480       Lowest
                                     S-type              4600                           2540       Lowest
                                    Kevlar
                                     29                   2800                          1440       High
                                     49                   2800                          1440       High
                                      129                 3200                          1440       High
                                    Nextel
                                      312                 1630                          2700       High
                                      610                 2770                          3960       High
                                    Spectra
                                      900                 2270                           970       High
                                      1000                2670                           970       High
                                      2000                3240                           970       High
                                    Alumina (Al2O3)       1900                          3900       High
                                                                            1
                                    Silicon carbide       3500                          3200       High
                                                            Matrix                  lg   fl  Tungsten diameter
                                    Note: These properties vary significantly depending on the material and method of preparation.

                                                    L gv-g Kevlar fibers
                                                       'yi
                                                        i’r"frs

                                                      Graphite fibers                   of   0.012 mm
                                                                                             Boron diameter
                                                                                  5,
                                                                                             0.1 mm
                                                                                             Mali”

                                              (G)                                (D)

                                    FIGURE 9.4  (a) Cross section of a tennis racket, showing graphite and aramid (Kevlar)
                                    reinforcing fibers. Source: Courtesy of ]. Dvorak, Mercury Marine Corporation; and F. Garrett,
                                    Wilson Sporting Goods Co. (b) Cross section of boron fiber-reinforced composite material.



                                    Carbon Fibers.  Carbon fibers (Fig. 9.4a), although more expensive than glass
                                    fibers, have a combination of low density, high strength, and high stiffness; the prod-
                                    uct is called carbon-fiber reinforced plastic (CFRP). Although the words often are
                                    used interchangeably, the difference between carbon and graphite depends on the
                                    purity of the material and the temperature at which it was processed. Carbon fibers
                                    are at least 90% carbon; graphite fibers are usually more than 99% carbon. A typi-
                                    cal carbon fiber contains amorphous (noncrystalline) carbon and graphite (crys-
                                    talline carbon). These fibers are classified by their elastic modulus, which ranges
                                    from 35 to 800 GPa, as lou/, intermediate, high, and 1/ery high modulus. Some trade
                                    names for carbon fibers are Celion and Thornel; see Fig. 9.3.
                                         All carbon fibers are made by pyrolysis of organic precursors, commonly
                                    polyacrylonitrile (PAN) because of its low cost. Rayon and pitch (the residue from
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