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7.13 Grain Growth  •  241


              Atomic diffusion
              across boundary

                                                                              850 C
                                                                                              800 C
                                                           1.0
                                                                                              700 C
                                                        Grain diameter (mm)  (Logarithmic scale)  0.1  600 C




                                                                                              500 C



                                                          0.01
                                                             1         10        10 2       10 3      10 4
                       Direction of grain                                      Time (min)
                       boundary motion                                       (Logarithmic scale)
              Figure 7.24  Schematic representation   Figure 7.25  The logarithm of grain diameter versus the
              of grain growth via atomic diffusion.   logarithm of time for grain growth in brass at several
              (Adapted from L. H. Van Vlack, Elements of   temperatures.
              Materials Science and Engineering, 6th edition. ©   (From J. E. Burke, “Some Factors Affecting the Rate of Grain Growth
              1989 by Addison-Wesley Publishing Company, Inc.)  in Metals.” Reprinted with permission from Metallurgical Transactions,
                                                      Vol. 180, 1949, a publication of The Metallurgical Society of AIME,
                                                      Warrendale, Pennsylvania.)



                                 grain structure of a single-phase alloy is coarser than that desired, refinement may be
                                 accomplished by plastically deforming the material, then subjecting it to a recrystalliza-
                                 tion heat treatment, as described previously.

                        EXAMPLE PROBLEM 7.3

                          Computation of Grain Size after Heat Treatment
                                                                                3
                          When a hypothetical metal having a grain diameter of 8.2   10  mm is heated to 500 C for
                          12.5 min, the grain diameter increases to 2.7   10  mm. Compute the grain diameter when a
                                                                    2
                          specimen of the original material is heated at 500 C for 100 min. Assume the grain diameter
                          exponent n has a value of 2.
                          Solution
                          For this problem, Equation 7.9 becomes
                                                               2
                                                          d - d 0 = Kt                             (7.10)
                                                           2
                          It is first necessary to solve for the value of K. This is possible by incorporating the first set of
                          data from the problem statement—that is,
                            d 0    8.2   10  mm
                                       3
                                       2
                             d   2.7   10  mm
                             t   12.5 min
                          into the following rearranged form of Equation 7.10:
                                                                 2   2
                                                                d - d 0
                                                           K =
                                                                   t
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