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66                                          Chapter 3  A Survey of Engineering Materials


               In this chapter, each major class of materials is considered in more detail. Groups of related
            materials within each major class are identified, the effects of processing variables are summarized,
            and the systems used for naming various materials are described. Metals and alloys are the dominant
            engineering materials in current use in many applications, so more space is devoted to these than to
            the others. However, polymers, ceramics and glasses, and composites are also of major importance.
            Recent improvements in nonmetallic and composite materials have resulted in a trend toward these
            replacing metals in some applications.
               An essential part of the process of engineering design is the selection of suitable materials
            from which to make engineering components. This requires at least a general knowledge of
            the composition, structure, and characteristics of materials, as summarized in this chapter. For a
            particular engineering component, the choice among candidate materials may sometimes be aided
            by systematic analysis, for example, to minimize mass or cost. Such analysis is introduced near
            the end of this chapter. Materials selection is also aided by specific prediction of strength, life,
            or amount of deformation, as described in later chapters related to yielding, fracture, fatigue,
            and creep.

            3.2 ALLOYING AND PROCESSING OF METALS

            Approximately 80% of the one-hundred-plus elements in the periodic table can be classed as
            metals. A number of these possess combinations of availability and properties that lead to their
            use as engineering metals where mechanical strength is needed. The most widely used engineering
            metal is iron, which is the main constituent of the iron-based alloys termed steels. Some other
            structural metals that are widely used are aluminum, copper, titanium, magnesium, nickel, and
            cobalt. Additional common metals, such as zinc, lead, tin, and silver, are used where the stresses
            are quite low, as in various low-strength cast parts and solder joints. The refractory metals, notably
            molybdenum, niobium, tantalum, tungsten, and zirconium, have melting temperatures somewhat
            or even substantially above that of iron (1538 C). Relatively small quantities of these are used as
                                                 ◦
            engineering metals for specialized applications, particularly where high strength is needed at a very
            high temperature. Some properties and uses for selected engineering metals are given in Table 3.1.
               A metal alloy is usually a melted-together combination of two or more chemical elements,
            where the bulk of the material consists of one or more metals. A wide variety of metallic and
            nonmetallic chemical elements are used in alloying the principal engineering metals. Some of
            the more common ones are boron, carbon, magnesium, silicon, vanadium, chromium, manganese,
            nickel, copper, zinc, molybdenum, and tin. The amounts and combinations of alloying elements used
            with various metals have major effects on their strength, ductility, temperature resistance, corrosion
            resistance, and other properties.
               For a given alloy composition, the properties are further affected by the particular processing
            used. Processing includes heat treatment, deformation, and casting. In heat treatment, a metal or
            alloy is subjected to a particular schedule of heating, holding at temperature, and cooling that causes
            desirable physical or chemical changes. Deformation is the process of forcing a piece of material
            to change its thickness or shape. Some of the means of doing so are forging, rolling, extruding,
            and drawing, as illustrated in Fig. 3.1. Casting is simply the pouring of melted metal into a mold
            so that it conforms to the shape of the mold when it solidifies. Heat treatment and deformation or
            casting may be used in combination, and particular alloying elements are often added because they
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