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202  Membranes for lndustrial  Wastewater Recovery and Re-use

          effluent treatment can be found in El-Halwagi (1992) and Wang et al. (1994b).
          The case study illustrates the importance of software tools, comprising the water
          pinch methodology, to provide ideas promoting an integrated approach. It will
          be shown that, using available data from different purification techniques,  the
          software  package  reveals  the  most  cost-effective  selection  of  segregated
          purification  techniques  and  end-of-pipe  treatment  both  to  comply  with  the
          stringent effluent standards and to minimise the overall water consumption. The
          program  allows the insertion  of  as many purification  techniques  as is desired,
          since  it  is  not  known  in  advance  which  purification  technologies  or  the
          combination thereof provide the greatest cost benefit.

          The textile process
          Textile processing has been discussed in Section 2.3. It consists of many different
          steps, nearly all of them generating wastewater. The amount and composition of
          these individual effluent streams depends on many different factors, including
          the  processed  fabric  and  the  process  used  (Bisschops, 2002). Due  to  more
          stringent effluent constraints and the increasing cost of water usage, much effort
          has been devoted to minimising water usage and improving product recovery in
          the textile industry.
            A general flowchart of  a textile manufacturing process comprises (Bisschops,
          2002):

               Desizing with high BOD, COD and SS effluent concentrations,
                Scouringlwashing with high BOD, COD, SS effluent concentrations,
                Bleaching with low BOD, high COD and solids effluent concentrations,
                Singeing where only cooling water is needed,
                Cotton mercerising with low BOD and SS effluent concentrations,
               Dyeing with very high COD and high SS effluent concentrations, with BOD
               levels dependent upon dye biodegradability,
               Printing with very high COD and high SS effluent concentrations and BOD
                levels dependent upon dye biodegradability, and
                Finishing  where waters vary  widely  according  to  the type  of  finishing
               process and information regarding effluent concentrations and flow rates
                are scarce.

            Apart form the water usage in these different process steps, water is used in the
          process  for  washing  after  pretreatment  steps,  after  dyeing  and  after  some
          finishing steps. Water is used for utilities such as raising steam, general cooling
          and maintenance.
          Process data
          The pure water source available for the processes  is groundwater having  the
          following specification with respect to six key contaminants:

            e  5ppmSS,
            0   10 Pt-Co colour,
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