Page 247 - Methods For Monitoring And Diagnosing The Efficiency Of Catalytic Converters A Patent - oriented Survey
P. 247

Other Methods                          229




                    and on the flux of gas that  flows through the converter. More specifically the values (Ox,
                    Red) are calculated by making use  of the following formulas:


                    if  v>O:  Ox=v//K                   and  Red  = 0



                    if v< 0:  ox = 0                   and  Red  = -v / K ’


                    where:
                   K and K’ are characteristic parameters of the downstream oxygen sensor.

                    The chemical kinetics (clr c2) of the reactions are calculated by making use of the
                    following formulas:







                                              C2
                   c2  -=  k2    (0.5~ x)~~ (x, y, v)
                                      f
                                           ~
                   where:
                   kl, al, bl and k2, a2, b2 are the characteristic parameters of the two reactions
                 5) estimating the concentration (2) of the oxygen  downstream of the catalytic converter by
                   writing the low of variation of (z) in time:



                   dddt  = - K% /z(t) - I@)]  i  (K12e) /C1(x, y, I.’)  -  C2(x, y, I.’)]


                   where:
                   L is the length of the catalytic monolith
                   e is the void fraction of the monolith
                 6) estimating the quantity of oxygen (x) stored in the converter by means of the formula:







                 7) calculating the value of (y) by  taking into account the difference of the measured  (v) and
                   calculated value (2) of oxygen  content in the exhaust gas. The following formula is used:
   242   243   244   245   246   247   248   249   250   251   252