Page 41 - MODELING OF ASPHALT CONCRETE
P. 41

Modeling of Asphalt Binder Rheology and Its Application to Modified Binders      19


                           changing to non-Newtonian gradually as the shear rate or stress level increases
                           (Puzinauskas 1967). Therefore, the relation is not linear and the value of C will
                           depend on which range is referred to.
                         2. The parameter, being a measure of non-Newtonian behavior, will naturally
                           depend on the stress history. Majidzadeh and Schweyer (1965) conducted an
                           experiment where the C value was measured for the same asphalt under the
                           same conditions, but the sequence of loading applications was changed. They
                           compared C  measured when the load increments where added in a decreasing
                                     i
                           sequence of load values with “C “ measured with an increasing sequence of
                                                       d
                           load step values.
                         3.  In addition to the above problems with the C measure another point may be
                           added here. Constructing the stress-shear rate relation is subjected to the same
                           controversy associated with apparent viscosity. From a standard creep curve
                           measured for a non-Newtonian material, the shear rate may never come to an
                           equilibrium within reasonable time or strain level, therefore, the value of the
                           shear rate used to construct the stress-shear rate curve will depend on the time
                           of loading at which this rate is determined. In other words the C value is time
                           of loading dependent.

                    The Shear Index  Apparent viscosity is plotted versus shear rate on a log-log scale. The
                    slope of the relation between two different shear rates is determined and considered as
                    the shear susceptibility parameter.  Although early works tried to approximate the
                    relation as linear (Jimenez and Gallaway 1961; Gallaway 1959), a large number of more
                    recent studies showed clearly that this is not true. Apparent viscosity is constant up to
                    the Newtonian behavior limit after which the viscosity starts decreasing continuously
                    with increasing shear rate.
                       For asphalt aging studies, the shear index has been used by many researchers. Zube
                    and Skog (1969), Culley (1969), and Kandhal et al. (1973) all compared viscosity-shear
                    rate plots of unaged with lab or field aged asphalts. However, since the plots are
                    nonlinear and temperature dependent researchers selected different ranges of shear
                    rates and different temperatures. All agreed that an increase in the shear susceptibility
                    is observed upon aging.
                       As with other susceptibility parameters, the shear index may be considered as an
                    arbitrary value. The exact value depends, to a great extent, on the range of shear rate
                    considered and the temperature at which it is measured. A single shear index may only
                    indicate the type of behavior expected for an asphalt at the temperature and shear rate
                    range it is measured at; no simple extrapolation or even interpolation can be made.
                    Moreover, it still uses the apparent viscosity which is time of loading dependent and if
                    this is not constant then the plot is very difficult to interpret.
                       In summary, shear susceptibility parameters are not much better than temperature
                    susceptibility parameters, or even the single measurements. They are also arbitrary in
                    nature and do not show high promise for use in asphalt rheological characterization.

                    Linear Viscoelastic Properties
                    Although using rheological concepts to characterize asphalts dates back more than 50
                    years, the cost and availability of equipment hampered the spread of using viscoelasticity
                    to qualify asphalts and study effect of modifiers. This shortcoming was overcome
   36   37   38   39   40   41   42   43   44   45   46