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Modeling of Asphalt Binder Rheology and Its Application to Modified Binders      23


                    of loading of the pavement under traffic needs to be simulated in measurement to
                    obtain a reliable estimate of binder contribution to pavement performance.
                       The third temperature zone is the low-temperature zone at which thermal cracking
                    (Chaps. 14 and 15) is the prevailing failure mode. During thermal cooling, asphalt
                    stiffness increases continuously and thus results in higher stresses for a given shrinkage
                    strain. Simultaneously, thermal stresses relax due to viscoelastic flow of the binder. To
                    reliably predict binder contribution to cracking, both the stiffness of a binder and its
                    rate of relaxation need to be evaluated. The stiffness of the binder is directly proportional
                        ∗
                    to G  and the rate of relaxation is directly related to d. A lower stiffness and higher rate
                    of relaxation are favorable for resistance to thermal cracking. As with other temperature
                    zones, a single measure of the stiffness or viscosity of the binder is not sufficient to
                    select better binders that will resist cracking at the lowest pavement temperatures.
                       The above discussion of the relation between asphalt binder properties and pavement
                    performance is further complicated by the aging phenomenon. Asphalts are hydrocarbon
                    materials that oxidize in the presence of oxygen from the environment. This oxidation
                    process changes the rheological and failure properties of the asphalt. As shown in Fig. 2-2,
                                                                                        ∗
                    the rheological mastercurve slope decreases with aging, which indicates higher G  and
                    smaller d  values for the unaged binder at all temperatures. These changes translate into
                                    ∗
                    less sensitivity of G  and d  to temperatures or loading frequency and into more elastic
                    component (lower  d). Significant oxidation effects usually appear after considerable
                                        ∗
                    service life. Increased G  values and lower d values are favorable changes with respect to
                    rutting performance, but they are unfavorable for thermal cracking performance. For
                                                 ∗
                    fatigue cracking, the increase in G  is not favorable while the decreased d  is generally
                    favorable, depending on the type of pavement and mode of fatigue damage.


               Modeling of the Viscoelastic Properties of Asphalts
                    Many attempts have been made to use simple mechanical analog, such as the generalized
                    Burgers model and the Prony series, and phenomenological models, defined by curve
                    fitting of experimental data, to describe the viscoelastic properties. The latter approach
                    has seen more acceptance particularly with the advancement of computers and the
                    flexibility of these models. Some of the most notable models that followed the pioneering
                    work by Van der Poel in the early 1950s include work by Jongepier and Kuilman (1969)
                    who proposed that asphalts can be considered as simple liquids whose rheological behavior
                    can be approximated by log Gaussian distribution of relaxation times. These authors used
                    a width parameter to represent the dependency of rheological behavior on loading time
                    and an equiviscous temperature to represent the temperature dependence. Dickinson and
                    Witt (1974) reported a study related to the work done by Dobson (1969). The authors
                    proposed a new mathematical function for representing the loading-time dependency of
                    the rheological parameters and adopted the same mathematical functions developed by
                    Dobson for the temperature dependency (Dobson 1969). These early models were evaluated
                    in several following works, and the accuracy of the models have been tested using many
                    types of unaged as well as aged asphalts (Pink et al. 1980; de Bats and Gooswilligen 1995;
                    Maccarrone 1987). These researchers, although sometimes not consistent, in their
                    observation all agree that asphalts can indeed be represented as linear viscoelastic materials
                    that are thermorheologically simple. They also agree that to characterize such materials
                    two behaviors need to be defined: the dependency of rheology on loading time, and the
                    dependency of rheology on temperature.
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