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Sewage sludge ash                                                 127



















           Figure 5.3 SEM micrographs of SSA particles (Monzo ´ et al., 2003). SSA, Sewage sludge ash.


            Table 5.4 Chemical composition of sewage sludge ash from Pinedo (Spain)
            Oxide (%)                              Reference
                                Pe ´rez-Carrio ´n et al. (2014)  Baeza et al. (2014a)

            SiO 2               19.2                           16.98
            Al 2 O 3            8.9                            9.48
            Fe 2 O 3            10.0                           8.38
            CaO                 30.6                           29.73
            MgO                 2.7                            3.17
            Na 2 O              0.8                            0.92
            K 2 O               1.4                            1.26
                                1.0                            0.90
            TiO 2
                                12.3                           14.01
            P 2 O 5
            Cl 2                --                             0.15
                                11.1                           8.80
            SO 3
            Others                                             0.56
            LOI                 5.1                            4.55


           the characterisation of the ash was somewhat different than in previous studies
           (Table 5.4). In the X-ray pattern, various crystalline compounds [quartz SiO 2 , anhy-
           drite CaSO 4 , calcite CaCO 3 , forsterite Mg 2 SiO 4 , Magnetite, Fe 3 O 4 , lime CaO and
           whitlockite, β-Ca 3 (PO 4 ) 2 ] were identified, more so than an amorphous material.
                                                       2
           Ash particles had a specific Blaine surface of 3000 cm /g.
              Moreover, Baeza et al. (2014a) studied binary and ternary combinations of SSA
           with marble dust (MD), FA and RHA as a replacement for PC pastes. The chemical
           composition of the SSA was collected in Table 5.4. For this work, the ash used had
           a very small mean particle diameter (16.67 μm).
              Pan et al. (2003) investigated the effect of SSA fineness on mortar properties.
           This ash was taken from a wastewater treatment plant in Taipei City (Taiwan) and
           it was obtained from a typical sewage treatment plant using a primary process. The
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