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160                               New Trends in Eco-efficient and Recycled Concrete



            0.14  (A)           0% GC          0  (B)             0% GC
                                55% GC
                                                                  55% GC
                                55% GC+10% GP                     55% GC+10% GP
            0.12                             –200
           ASR expansion (%)  0.08  Standard limit  Drying shrinkage (*10 –6 )  –400
            0.10
                                             –600
            0.06
            0.04
            0.02                             –800
                                            –1000
            0.00
                                            –1200
              0        7       14       21      0     7     14     21     28
                         Age (days)                        Age (days)
         Figure 6.6 The effect of maximum content of glass cullet on the ASR and shrinkage of
         paving blocks. (A) ASR expansion (80 C 1 M NaOH solution); (B) Drying shrinkage (25 C


         and 50% humidity). ASR, Alkali silica-reaction.
         absorption of pedestrian blocks should not exceed 6.0%. The water absorption value
         of paving blocks with GC were less than 6.0%.
           Although the 14-day expansion values did not exceed the deleterious limit, the
         potential deterioration at longer ages as a result of ASR still need to be taken into
         consideration (see Fig. 6.6A). Therefore, 10% of cement was replaced by GP in
         order to mitigate the ASR expansion for the paving blocks. The experimental
         results showed that the inclusion of GP could significantly suppress expansion and
         the GP-blended paving blocks had comparable expansion values to the paving
         blocks without GC. The reason for the effectiveness in reducing the ASR expansion
         may be due to the fact that GP consumed more alkalis and free calcium hydroxide
         in solution to form a sodium-calcium-silicate hydrate gel, leading to lower expan-
         sion around the reactive aggregates (Shi et al., 2004). Another explanation was pro-
         posed by Ichikawa (2009) who stated that the rate of ASR was highly controlled by
         the particle size of reactive aggregate and that a grain size less than 50 μm (large
         specific surface area) would preferentially react with alkali hydroxide to prevent
         the formation of expansive pressure. On the basis of this size effect, the introduc-
         tion of GP with small particle size is, thus expected to suppress ASR. Fig. 6.6B
         shows the effect of GC on the drying shrinkage of paving blocks. When 55% of GC
         was introduced to replace the fine aggregates in the paving blocks, the drying
         shrinkage could be reduced effectively. The drying shrinkage values of the blocks
         produced with the maximum content of GC and 10% GP were about half of those
         of blocks without GC.




         6.5   Application of waste glass in OPC concrete

         Due to the non-absorbent nature of the GC, Kou and Poon (2009) made an attempt
         to investigate the feasibility of using recycled glass in the production of self-
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