Page 253 - Optofluidics Fundamentals, Devices, and Applications
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               When the mold is overfilled with fluid to produce a convex profile,
               plano-concave lenses can be molded. After one lens is molded, the
               liquid-filled mold can be tuned to another shape.
                  The roughness of the surface of the molded lens is measured using
               an optical interferometer (Veeco NT 1100). The root-mean-square
               (RMS) surface roughness of the molded PDMS lenses is less than
               6  nm. The surface quality is comparable to commercial lenses and
               adequate for most optical systems although more demanding optical
               systems may require an RMS roughness of less than 2 nm [75].
                  As discussed earlier, radius of curvature alone is not sufficient to
               describe the profile of the molded lenses. The lens profile can be more
               precisely represented by an aspherical function [Eq. (9-1)]. In order to
               fabricate aspherical lenses of designed profiles using the liquid-filled
               mold, both the curvature and the conic factor need to be precisely
               controlled. A simple calculation shows that the surface profile of an
               infinitely thin elastic membrane under fluidic pressure is parabolic,
               corresponding to a conic factor of −1 [79]. However, in reality, the
               elastic membrane has a finite thickness and shows nonlinear hyper-
               elastic behavior. Figure 9-23 shows that a wide range of conic factors
               can be obtained from different process and material parameters, such
               as membrane thickness and amount of prestretch, suggesting that a
               large family of focus-fixed aspherical lenses can be produced from a
               tunable liquid-filled mold.
                  Figure 9-23 represents various combinations of curvature and
               conic factor of the liquid-filled tunable mold [80]. Different extents of
               prestretch, for example, result in various combinations of conic fac-
               tors and curvatures. In this specific case, only positive conic factors
               are obtained. Negative conic factors can be obtained with different
               process parameters since the conic factor approaches −1 (e.g.,
               parabola) for infinitely thin elastic membrane [79]. Sophisticated
               membrane processing techniques other than thickness and prestretch
               offer possibilities for even more complicated lens profiles. These tech-
               niques include varying elastic constants and membrane thickness
               along the radial axis.

               9-4-2 Summary
               We have discussed a new way of fabricating aspherical polymer
               lenses using tunable liquid-filled molds. The surface roughness of the
               molded lenses is less than 6 nm, which is adequate for most optical
               systems. The curvature and the conic factor, two key parameters to
               define an aspherical lens, can be controlled by changing process
               parameters such as the applied pressure, the percentage of prestretch,
               the membrane thickness, and the mechanical constants of the
               membrane. This unique capability enables us to prototype an optical
               system in a cost-effective and time-efficient manner.
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