Page 27 - Origin and Prediction of Abnormal Formation Pressures
P. 27

10                   E.C. DONALDSON, G.V. CHILINGAR, J.O. ROBERTSON JR. AND V. SEREBRYAKOV

            (20  ft3/bbl)  (Kharaka  et  al.,  1977).  Organic  matter  which  is  a  substantial  part  of
            freshly  deposited  muds  decomposes  during  diagenesis  as  a  result  of biochemical  and
            thermochemical  processes.  The  resulting  methane  gas  which  is  released  during  the
            transformations  can  create,  or  accentuate,  the  overpressured,  undercompacted,  state
            of  the  compacting  mud  sediments  in  two  ways:  (a)  by  building  up  additional  pore
            pressure;  and  (b)  by  further  impeding  the  expulsion  of interstitial  pore  water through
            the development of a second gas-fluid phase.  Gas bubbles dispersed in water reduce the
            permeability of the rock to either phase (Chilingarian et al.,  1995).
               The mechanism of temperature increase (aquathermal expansion)  as a possible cause
            of  overpressures  has  been  questioned  by  several  authors  (e.g.,  see  Swarbrick  and
            Osborne,  1998). The main objection is the absence of practically impermeable seals.

            Phase changes that produce abnormal pressures

               Berner  (1980)  described  two  phases  in  early  diagenesis.  The  first  one  consisted  of
            two  stages:  (1)  the  initial  stage  which  is  regulated  by  the  chemistry  of water;  and  (2)
            the early burial  stage which is controlled by the entrapped pore water that is chemically
            modified  by  bacteria  and  bioturbation  of  surface  organisms.  During  the  initial  stage,
            the  clay  minerals  undergo  a  gradual  change  of  their  ionic  exchange  capacity,  and







                                                   Normal  thermal
                                                   gradient  18.2~
                                                   (I.O~    ft.)
                         .-.  6
                        if3
                         i
                         c)
                         x
                        I-
                        uJ  9                            Geothermal  zone
                        bJ    ,,=,                   /~30.OOC/km
                              a                          (I.7~    ft.)
                        -r-
                        l--
                        o.
                        w
                        ol2
                                                               \
                                                               \
                          16                                    \  \
                                                                  \
                                 -        50       I00      150      2_00
                                             TEMPERATURE  ~
                                 I    ,    I    ~   I    I    I   I
                                 0        I00      200      300
                                             TEMPERATURE  ~
                          Fig.  1-5. Approximate  average  subsurface  temperature  gradients.
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