Page 194 - Packed bed columns for absorption, desorption, rectification and direct heat transfer
P. 194

184


                           times the pressure drop even under the loading point. The reason is that the
                           formed froth occupies a significant part of the column free cross-section, which
                           leads to significant increasing of the gas velocity and therefore of the pressure
                           drop. The investigation shows the following:
                                  1. The froth is formed because of the transformation of a part of the
                           kinetic energy of the liquid flow in energy of foam connected with its larger
                           surface. That is why the generation of froth increases with increasing of the
                           liquid velocity, respectively of the liquid superficial velocity. But the increase
                           of the liquid velocity leads also to destroying of the already existing froth in the
                           packing.
                                  2. The foam stability, or the froth life, depends not only on the
                           composition of the liquid, but also on the hydrodynamie regime in the
                           apparatus. It is found, for example, that when we have two foam forming
                           liquids and two methods of measurement of their foam stability, if the stability
                           for the first liquid according to one of these methods is higher, according to the
                           other it can be measured as lower.
                                  3. The increasing of the gas velocity also acts in direction of forming
                           and destroying of the foam,
                                  4. A mechanism and a mathematical model for calculating the pressure
                           drop of foam forming liquids is presented and experimentally proved.
                                  5. It is predicted and experimentally proved that in a packing with long
                           vertical walls on which the liquid is fed with proper low velocity almost parallel
                           to the packing surface, froth is not formed.
                                  Nevertheless that it is possible to build a packed bed column able to
                           operate in presence of from forming substances, it is better to use anti-foaming
                           agents to prevent foaming than to construct the column so as to operate with
                           foam forming liquids.
                                  For calculation of the pressure drop under and over the loading point of
                           irrigated packings Billet and Schultes [316] offered the following equation:


                            4F       (64       1.8       )( -H f(H T
                                                               t
                                                                    t
                                                           S

                                    13300
   189   190   191   192   193   194   195   196   197   198   199