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12.4  THERMAL SLIDE                                                  209



                                                 s- ----






          Figure 75:   Profile of velocities of the fluid  in a capillary for the thermal slide


         the developing temperature profile  (93].  The given  temperature profile is  caused
         by  different  degrees  of compression of the  medium  by  the  propagating pressure
         wave.  Since the temperature of the medium is proportional to pressure (8.17), and
         consequently the gradient oftemperature is proportional to the gradient of pressure
         \lT "'  \lp,  it  follows  that  the  maximal  velocity  of thermal  slide  compensating
         Poiseuille  flow  is  directed  as  \lp,  i.e.,  as  k.  Under  the  outlined  assumptions,
         the  presence  of thermal  slide  along  the  capillary  surface  results  in  the  velocity
         profile represented schematically in  fig.  75.  This profile can be described  by  the
         relationship

                 v(ro) = -(1/4tt)\lp[(r- bt) 2   - r~] +  "Yr\7T1J[ro  - (r- bt)]   (12.19)

         where  Ot  is  the  thickness  of the  thermal  flow  layer,  which  has  the  order of the
         diffusion layer thickness  (93]  (the latter is equal to several times the free  path for
         molecules of the fluid);  "YT  is  the proportionality factor  in  the expression for  the
         velocity  of thermal  slide  (93]  vr  =  "Yr\lT;  17(·)  is  Heavyside's  function.  Using
         (12.19), compute the flow  of fluid  in a capillary

                                            r
                                   q =  21fPJ j v(ro) ro dro
                                           0
         Having set it to zero, we  obtain the correlation between the gradients of pressure
         and temperature
                                                                           (12.20)

         Dissipation of energy due to the internal friction for Poiseuille flow  (per unit length
         of a capillary) equals
                                           r
                                                   2
                                 E1  =  27f/L J  (8vf8ro) ro dro           (12.21)
                                          0
         The corresponding heating of the fluid with specific heat cr by !::.T degrees absorbs
         the energy equal to
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