Page 81 - Percolation Models for Transport in Porous Media With
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4.3  MIXED WETTABILITY                                                73

         if the lower  limit  in  the first  term of ( 4.27)  is  set  to equal 0  when  a  < 0,  and
         the normalizing condition for  f(r)  is taken into account.  The function rcb(rk2) is
         still determined from the condition (4.28) and assumes values from 0 to rc, as rk2
         varies between rc2  and 0.  Thus in this case the displacement of phase a by phase
         b is identical  to the case described  above,  with  cos fh  > 0,  cos 02 > 0,  and the
         formulas (4.29)- (4.31) for kb  remain valid.  Note only that since a< 0, the lower
         limits of integration in  (4.30)  and  (4.31),  formally,  are in  the domain of r  < 0,
         where, obviously, /(r) is defined to vanish.
            Now let ~t ~ ec·  In this case, the ICB formation from the capillaries of the first
         type is possible as early as the imbibition stage.  When -oo < Pk  < 0,


                                                                            (4.32)


            After substituting (4.32) into (1.7) we obtain the following condition for deter-
         mining Tcb(rkt)





            For reb  to be greater than zero, it is necessary that rk1 exceed its limiting value
         rclb  which is defined  by the condition for  the start of the flow  for  phase bin the
         capillaries of the first type,
                                       rctb
                                     K, J f(r)dr = ec
                                       0
            Thus when Pk  < 0, it can be found from  (4.32) and (2.1) that

                                 kb(rkt) = 0,  0 < Tkt  < rc1b,  -oo < Pk  < Pclb,
            k,(r.,) =A'/ Ko l[lf•(r)dr] ~•(•'1'/(r) dr (l f(r) ~) -~r',



                                              Tclb  ~ ru < oo,  Pclb  ~ Pk  < 00

            When the capillary pressure exceeds zero some of the capillaries of the second
         type being filled  with phase b associate with the ICB, while all capillaries of the
         first  type are by  that  time filled  with  this  phase.  The technique of the further
         calculations of the change of kb(rk2) is identical to the one used for the case when
         K,  > ec·  It is still described by formulas  (4.30)  and (4.31), where rc2 = 00 and Tcb
         is found from  the condition (4.28).
            We  shall  use  the  same  scheme  to  study  the  quantity  ka.  Let  cos01  > 0,
         cos02  > 0,  cos02  ~ cos01.  The distribution  function  for  phase  a  (the shaded
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