Page 239 - Petrophysics 2E
P. 239

2 12   PETROPHYSICS: RESERVOIR ROCK PROPERTIES



                                                 TABLE 4.3
                            CONCENTRATION CORRELATION CONSTANTS FOR  EQUATION 4.13

                                         Range of Concentration of NaCl Solution,
                    Concentration
                      Correlation                       csrn (mow
                       Constant      1 ,000-4 to lo-'    0.09 to 1.1      1.0 to 5.35

                           a1         9.42203 x  lo-'   9.33134 x lo-'   9.33292 x  lo-'
                          a2            8.889 x  lo-'   8.47181 x lo-'   8.45971 x  lo-'
                          a3        -2.72398  x  lop2   -1.04563  x lo-'   -910632  x  lo-'
                          a4        -2.25682  x lop3   -7.05334  x lop2  -2.27399  x  lo-'
                          a5          1.46605 x        -2.35562  x lop2   2.27456 x  lo-'
                           ac         0                 0               -3.81035  x  lo-'



                    of  NaCl solutions. For a given concentration of NaCl solution in mol&
                    Csm, the water resistivity at 25°C is:










                    where:          X,  = concentration correlation function.
                                   Csm = concentration of NaCl solution, mom.
                             al, . . . , a6  = correlation constants.

                       Table  4.3  shows  the  value  of  the  correlation  constants for  three
                    ranges of concentration: low4 < CSmlO-',  0.09 < C,,   < 1.4, and 1.0 <
                    Csm  < 5.35.
                       Arp's equation for calculating Rw  at any reservoir temperature T in
                     degrees Celsius is:


                                                                                  (4.14)



                       If  the  concentration of  NaCl  solution  is  given  in  ppm,  then  it  is
                     necessary to convert it to mol&  in order to solve for the concentration
                     correlation  function  Xc  and  then  Rw25.  The  conversion  equation
                    between ppm and mol/L is [4] :


                                                                                  (4.15)
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