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EVALUATION OF WETTABILITY             377


                                                        TABLE 6.2
                           WETTABlLlTY  TESTS FOR WATER-WET  AND  MIXED WETTABlLlTY  CORES  (CLOSE  TO
                             “NEUTRAL” WETTABILIN)  USING THE COMBINED USBM~AMOTT WETTABlLlN
                             TEST AND CONTACT ANGLE MEASUREMENTS. (AFTER SHARMA AND WUNDERLICH
                                                 [48]-TABLES   111 AND  Iv)

                                  Displacement of    Displacement of     USBM
                           No.    Water (Amott)         Oil (Amott)      Index     @A     OR
                                                  Water-wet Samples

                            1            0                 0.92           1.6      -       -
                            2            0                 0.80           1.2     26”     6”
                            3            0                                0.89     -      1.4”

                                              Mixed Wettability Samples
                            1           0.24               0.015          0.3      -       -
                            2           0.24               0.073          0.3     167”    145”
                            3           0.24               0.065          0.3      -       -


                           indicates very strong water wettability. The mixed wettability systems,
                           however, imbibe oil at S,  = 1.0 and water at Siw; the USBM index shows
                           that these cores are near the point of “neutral” wettability (oil-wet cores
                           have negative USBM wettability indices).

                    SPONTANEOUS IMBIBITION WETTABILITY TEST

                             Observations of spontaneous imbibition led to the conclusion that the
                           amount and rate of  imbibition are related to the overall wettability of
                           the porous system. The Amott wettability test is based in part on fluid
                           displacements caused by imbibition. However, it was recognized that the
                           rate of imbibition was influenced by several parameters: fluid viscosities,
                           shape and boundary conditions of  the core, porosity, permeability, and
                           interfacial tension. Zhang et al. applied the scaling equation that was
                           used by Mattox and Kyte for correlation of  oil recovery by  imbibition
                           into fractured reservoirs to analyses of  the rates of  imbibition of  cores
                           at  controlled states of  wettability from  strongly water  wet  to  mixed
                           wettability [25, 521. The scaling equation was generalized by using the
                           geometric average of the fluid viscosities and a characteristic core length,
                           L,,  that compensates for size, shape, and boundary condition. Ma  et al.
                           correlated oil recovery by spontaneous imbibition to dimensionless time
                           defined as [ 531 :


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