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Electrons and Photons

          16   Introductory Concepts

            Electrons have momentum, but can they have a wavelength? Well if
          your name were Prince Louis-Victor, Duke de Broglie, and the year
          was 1924, maybe such an idea would not seem so strange. If this were
          the case, then the energy of an electron would be

                                        1    h 2
                                   E =     ·
                                       2m      2
            Using this equation, you could actually calculate the wavelength if
          you knew the electron energy. Suppose your electron has an energy of
          1 eV. This is the energy of an electron that falls through a potential of
          1 V.

                              1 eV = 1.6 × 10 –19  joules
                     h             6.6 × 10 –34  joule-sec
                =         =                                   = 12 Å



                                                     –19
                                       –31
                   2 mE      2  ·  9  ×  1 0   kg  ·  1 .6  ×  1 0   jo u le s
          In 1929, de Broglie received the Nobel prize for this revolutionary
          idea. His reasoning was different from the simple analysis above, and
          involved little math, not to mention Maxwell’s equations. His insight
          was based on an analogy with his everyday experience and is present-
          ed later on in Section 2.6. Nearly ten years later, in 1937, the Nobel
          prize was awarded to Clint Davisson for his observation of electron
          diffraction, a property of electrons that can be described only by its
          fundamental wave-like nature. His lab partner, Lester Germer, got
          left out of the prize list, a mystery to this day.
            The work of Davisson and Germer led directly to the invention of
          the electron microscope, a widely used instrument in all branches of
          materials physics and engineering.

                          For a 1 eV photon,   = 12,400 Å
                            For a 1 eV electron,  = 12 Å

                                               photon
                        At 1 eV energy (only),      = 1000
                                               electron
          This ratio depends on the electron energy. But 1 eV is characteristic of
          electrons in solids. What does this mean?
            Relative to the electron, the photon has mostly energy, but not very
          much momentum. We can see this on the diagram of energy and mo-
          mentum (Fig. 2.4).
            Except for the uninteresting case in which E = 0, the energy mo-
          mentum curves for free electrons and photons do not intersect. That
          is: there is no point on the curves where the energy and momentum of
          an electron are equal to the energy and momentum of a photon. This




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