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134                                  Mechanical Behaviour of Plastics

                       2.20 Creep Failure of Plastics
                       When  a  constant stress is  applied  to  a  plastic  it  will  gradually  change  in
                       size due to the creep effect which was described earlier. Clearly the material
                       cannot continue indefinitely to get larger and eventually fracture will  occur.
                       This behaviour is referred to as Creep Rupture although occasionally the less
                       acceptable (to engineers) term of Static Fatigue is used. The time taken for the
                       material to fracture will depend on the stress level, the ambient temperature,
                       the type of environment, the component geometry, the molecular structure, the
                       fabrication method, etc. At some stresses the creep rate may be sufficiently low
                       that for most practical purposes the endurance of the material may be regarded
                       as  infinite. On  the other hand,  at high  stresses the material is likely to fail
                       shortly after the stress is applied.
                         The  mechanism  of  time-dependent failure  in  polymeric  materials  is  not
                       completely understood and  is  the  subject of  much  current research.  In  the
                       simplest terms  it  may  be  considered that  as the  material creeps, the  stress
                       at  some point  in  the  material becomes  sufficiently high  to  cause a  micro-
                       crack to develop but not propagate catastrophically. The stress in the remaining
                       unbroken section of  the material will than be increment4 by a small amount.
                       This causes a further stable growth of the microcrack so that over a period of
                       time the combined effects of  creep and stable crack growth cause a build up
                       of true stress in the material. Eventually a stage is reached when the localised
                       stress at the crack reaches a value which the remaining cross-section of  the
                       material is unable to sustain. At this point the crack propagates rapidly across
                       the whole cross-section of the material.
                         Creep rupture data is usually presented as applied static stress, 0, against the
                       logarithm of time to fracture, t, as shown in Fig. 2.71. If  fracture is preceded
                       by phenomena such as crazing (see Section 2.20.2), whitening and/or necking,
                      then it is usual to indicate on the creep rupture characteristics the stage at which
                       these were first observed. It may be seen from Fig. 2.71 that the appearance
                       of  crazing or whitening is not necessarily a sign the fracture is imminent. In
                       many  cases the material can continue to sustain the applied load for weeks,
                       months or even years after these phenomena are observed. However, there is
                       no doubt that when a load bearing component starts to craze or whiten, it can
                       be disconcerting and so it is very likely that it would be taken out of  service
                       at this point. For this reason it is sometimes preferable to use the term Creep
                       Failure rather than creep rupture because the material may have been deemed
                      to have failed before it fractures.
                         Isometric  data  from  the  creep curves may  also  be  superimposed on  the
                      creep rupture  data in  order to  give  an  indication of  the magnitudes of  the
                       strains involved. Most plastics behave in a ductile manner under the action of
                       a steady load. The most notable exceptions are polystyrene, injection moulding
                      grade acrylic and glass-filled nylon. However, even those materials which are
                      ductile at short times tend to become embrittled at long times. This can cause
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