Page 152 - Plastics Engineering
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Mechanical Behaviour of  Plastics                               135
























                                   Log time to failure (s)
                                      Fracture
                              ---     Whitening or crazing
                              ----- Isometric curves
                       Fig. 2.71  Qpical creep rupture behaviour of plastics

        difficulties in the extrapolation of short-term tests, as shown in Fig. 2.71. This
        problem has come to the fore in recent years with the unexpected brittle fracture
        of  polyethylene pipes after many  years of  being subjected to moderate pres-
        sures. On  this basis the British  Standards Institution (Code of  Practice 312)
        has given the following stresses as the design values for long term usage of
        plastics.
         Plastic                Safe working stresses
          LDPE                     2.1  m/m2
          HDPE                     5.0  MN/m2
          PP                       5.0  MN/m2
          ABS                      6.3  MN/m2
          UPVC                     10.0-  12.0 MN/m2

          Other factors which promote brittleness are geometrical discontinuities (stress
        concentrations) and aggressive environments which are likely to cause ESC (see
        Section 1.4.2). The absorption of fluids into plastics (e.g. water into nylon) can
        also affect their creep rupture characteristics, so advice should be sought where
        it is envisaged that this may occur.
          It may be seen from Fig. 2.71 that in most cases where the failure is ductile
        the isometric curves are approximately parallel to the fracture curve, suggesting
        that  this  type of  failure is  primarily  strain  dominated.  However,  the  brittle
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