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352                     Refining Biomass Residues for Sustainable Energy and Bioproducts


           diethanolamine, aminoethoxyethanol (DGA), etc. Amine scrubbing generally consists of
           an absorber and a stripper unit. The process provides efficient removal of H 2 S and CO 2 .
           In membrane separation, permeable membranes are used that enrich concentration of
           methane by trapping the other impure gases.
            In fermentation, distillation is the most common technique used for liquid biofuels upgra-
           dation. It works on the principle of volatile nature of substances. The separation of more
           volatile compounds occurs primarily from less volatile heavy compounds. The various
           types of distillation, conventional distillation, azeotrpic distillation, extractive distillation,
           and molecular distillation are used for products upgradation. Other purification technolo-
           gies include absorption, adsorption, super critical fluid extraction, and liquid liquid
           extraction. Currently, adsorption with molecular sieve for bioethanol purification is gain-
           ing attention because the process requires less energy input than distillation process.
           Biobutanol and bioethanol are also purified by membrane technology (pervaporation) and
           gas stripping method (Pulyalin et al., 2015).

           The upgraded end products from the abovementioned processes have utility in
         various fields and can become an effective substitute for the available energy
         resources.


         15.7   Conclusion


         India generates enormous amount of agricultural wastes every year and it affects its
         economical growth if these wastes are not utilized in a proper way. In appropriate
         collection, open dumping of these affects the environmental condition and also the
         human health. Several problems associated with the biomass include high moisture,
         low calorific value, large particle size, different composition, etc. Effective pretreat-
         ment can solve these basic problems but there is a need to think for waste to bioe-
         nergy approach for effective utilization of agricultural wastes. Various techniques
         (pyrolysis, gasification, AD, etc.) are available for the bioenergy generation.
         Research in the field of upgradation of products to high-energy feedstock and its
         successful utilization will lessen the load on the fossil fuels. However, awareness
         among the people about these processes is very less and they pay little attention in
         utilizing renewable energy sources. Therefore there is a need of promoting R&D
         activities on utilizing the agricultural wastes that will not only reduce the amount of
         these wastes but it will also open the doors for bioenergy generation which decrease
         the gap between demand and supply of energy. MNRE has installed various bio-
         mass power generation plants along with many gasification plants in various states
         of India for effective utilization of local available biomass wastes.


         Acknowledgment


         The authors acknowledge the necessary facilities provided by the Department of Chemical
         Engineering and Technology, Indian Institute of Technology (BHU), Varanasi, for undertak-
         ing this work.
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