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Limestone    33


                                                              present consensus is that they form by chemical pre-
                                                              cipitation out of agitated water saturated in calcium
                                                              carbonate in warm waters (Tucker & Wright 1990). It
                                                              is likely that bacteria also play a role in the process,
                                                              especially in less agitated environments (Folk & Lynch
                                                              2001). Concentrically layered carbonate particles
                                                              over 2 mm across are called pisoids: these are often
                                                              more irregular in shape but are otherwise similar in
                                                              form and origin to ooids.
                                                               Some round particles made up of fine-grained cal-
                                                              cium carbonate found in sediments do not show any
                                                              concentric structure and have apparently not grown
                                                              in water in the same way as an ooid or pisoid. These
                                                              peloids are commonly the faecal pellets of marine
                              	                               organisms such as gastropods and may be very abun-

                                                              dant in some carbonate deposits, mostly as particles
                                                              less than a millimetre across. In thin-section these
                                                              pellets are internally homogeneous, and, if the rock
                                                              underwent some early compaction, they may have
                                                              become deformed, squashed between harder grains,
                                                              making them difficult to distinguish from loose mud
                                                              deposited as a matrix.
                                                
  
           Intraclasts are fragments of calcium carbonate

                                                              material that has been partly lithified and then
                 Fig. 3.5 Non-biogenic fragments that occur in limestones.  broken up and reworked to form a clast which is
                                                              incorporated into the sediment. This commonly
                                                              occurs where lime mud dries out by subaerial expo-
                                                              sure in a mud flat and is then reworked by a current.
                 debris and alter the original structure of a shell into a  A conglomerate of flakes of carbonate mud can be
                 fine-grained micrite (micritisation).        formed in this way. Other settings where clasts of
                                                              lithified calcium carbonate occur are associated with
                                                              reefs where the framework of the reef is broken up by
                 3.1.4 Non-biogenic constituents of limestone  wave or storm action and redeposited (15.3.2). Car-
                                                              bonate grains consisting of several fragments cemen-
                 A variety of other types of grain also occur commonly in  ted together are aggregate grains, which when they
                 carbonate sediments and sedimentary rocks (Fig. 3.5).  comprise a collection of rounded grains are known as
                 Ooids are spherical bodies of calcium carbonate less  grapestones.
                 than 2 mm in diameter. They have an internal struc-
                 ture of concentric layers which suggests that they
                 form by the precipitation of calcium carbonate around  3.1.5 Carbonate muds
                 the surface of the sphere. At the centre of an ooid lies
                 a nucleus that may be a fragment of other carbonate  Fine-grained calcium carbonate particles less than
                 material or a clastic sand grain. Accumulations of  4 microns across (cf. clay: 2.4) are referred to as
                 ooids form shoals in shallow marine environments  lime mud, carbonate mud or micrite. The source
                 today and are components of limestone throughout  of this fine material may be purely chemical preci-
                 the Phanerozoic. A rock made up of carbonate ooids is  pitation from water saturated in calcium carbo-
                 commonly referred to as an oolitic limestone,  nate, from the breakdown of skeletal fragments, or
                 although this name does not form part of the Dunham  have an algal or bacterial origin. The small size of
                 classification of carbonate rocks (3.1.6). The origin of  the particles usually makes it very difficult to deter-
                 ooids has been the subject of much debate and the  mine the source. Lime mud is found in many
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