Page 53 - Sedimentology and Stratigraphy
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40    Biogenic, Chemical and Volcanogenic Sediments


                                                              concentrations of organic material are of considerable
                                                              economic importance: coal, oil and gas are all prod-
                                                              ucts of the diagenetic alteration of organic material
                                                              deposited and preserved in sedimentary rocks, and the
                                                              processes of formation of these naturally occurring
                                                              hydrocarbons are considered further in 18.7.


                                                              3.6.1 Modern organic-rich deposits

                                                              Most of the dead remains of land plants decompose at
                                                              the surface or within the soil as a result of oxidation,
                                                              microbial or animal activity. Long-term preservation
                  Fig. 3.11 Thinly bedded banded iron formation (BIF) com-  of dead vegetation is favoured by the wet, anaerobic
                  posed of alternating layers of iron-rich and silica-rich rock.  conditions of mires, bogs and swamps and thick accu-
                                                              mulations of peat may form. Peats are forming at the
                  of lines of evidence that the atmosphere contained little  present day in a wide range of climatic zones from
                  or no oxygen through much of Precambrian times.  subarctic boggy regions to mangrove swamps in the
                                                              tropics (McCabe 1984; Hazeldine 1989) and contain
                                                              a range of plant types, from mosses in cool upland
                  3.5.4 Ferromanganese deposits               areas to trees in lowland fens and swamps. Thick peat
                                                              deposits are most commonly associated with river
                  Nodules or layers of ferromanganese oxyhydroxide  floodplains (9.3), the upper parts of deltas (12.3.1)
                  form authigenically on the sea floor: they are black to  and with coastal plains (13.2.2). Pure peat will form
                  dark brown in colour and range from a few millimetres  only in areas that receive little clastic input. Regular
                  to many centimetres across as nodules or as extensive  flooding from rivers or the sea will introduce mud into
                  laminated crusts on hard substrates. Although these  the peat-forming environment and the resulting
                  manganese nodules form at any depth, they form  deposit will be a carbonaceous mudrock.
                  very slowly and are only found concentrated in deep  The accumulation of organic material in subaque-
                  oceans (16.5.4) where the rate of deposition of any  ous environments is just as important as land depos-
                  other sediment is even slower (Calvert 2003).  its. Sapropel is the remains of planktonic algae,
                                                              spores and very fine detritus from larger plants that
                                                              accumulates underwater in anaerobic conditions:
                  3.6 CARBONACEOUS (ORGANIC)                  these deposits may form a sapropelic coal (18.7.1).
                  DEPOSITS                                    Anaerobic conditions are also required to accumulate
                                                              the organic material that ultimately forms liquid and
                  Sediments and sedimentary rocks with a high propor-  gaseous hydrocarbons: these deposits are composed of
                  tion of organic matter are termed carbonaceous  the remains of zooplankton (microscopic animals),
                  because they are rich in carbon (cf. calcareous –  phytoplankton (floating microscopic algae) and bac-
                  3.1). A deposit is considered to be carbonaceous if it  teria. The formation of oil and gas from deposits of this
                  contains a proportion of organic material that is  type is considered in section 18.7.3.
                  significantly higher than average (>2% for mudrock,
                  >0.2% for limestone, >0.05% for sandstone). Organic
                  matter normally decomposes on the death of the plant  3.6.2 Coal
                  or animal and is only preserved under conditions of
                  limited oxygen availability, anaerobic conditions.  If over two-thirds of a rock is solid organic matter it
                  Environments where this may happen are water-  may be called a coal. Most economic coals have less
                  logged swamps and bogs (18.7.1), stratified lakes  than 10% non-organic, non-combustible material
                  (10.2.1) and marine waters with restricted circula-  that is often referred to as ash. Coal can be readily
                  tion such as lagoons (13.3.2). Strata containing high  recognised because it is black and has a low density.
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