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Quantum Mechanics of Single Electrons
                             where we used (3.15) and the fact that for the Hamilton operator
                                  ˆ ∗
                             ˆ
                             H =  H   holds. We use
                                                      —
                                               ˆ
                                                         2
                                               H =  –  -------∇ +  Ux()           (3.20)
                                                     2m
                             and
                                                          (
                                                   2
                                         2
                                      Ψ∇ Ψ∗ –  Ψ∗ ∇ Ψ =  ∇Ψ∇Ψ∗ –  Ψ∗ ∇Ψ)          (3.21)
                             which yields a continuity equation of the form
                                              d    2
                                               t d ∫  Ψ d V =  – ∫ ∇ j V          (3.22)
                                                               d
                                               Ω           Γ
                                  Γ
                             where   is the surface of the region Ω  . Here j is the current density vec-
                             tor, which is identified by

                                      i—                   1
                                  j =  ------- Ψ∇Ψ∗ –(  Ψ∗ ∇Ψ) =  ------- Ψp ˆ ∗ Ψ∗ –(  Ψ∗ p ˆ Ψ)  (3.23)
                                      2m                   2m
                Box 3.1.  The Gauss Theorem.

                 The Gauss Theorem. Consider a vector field   This is also true for situations where the volume is
                  Ar()   and a volume element   with a closed sur-  a non simply connected region, i.e., there may be
                                    V
                                    n
                                                           V
                 face S  . The normal vector   of the surface   holes in  .
                     V
                 points outward the volume element. Then we have   In components we formulate the theorem for arbi-
                 the following relation between the surface integral   trary dimensions D as follows
                 and the volume integral of the vector field           ∂
                                                           ∫ ° ds … =  ∫ d V ∂ x  …  (B 3.1.2)
                                                              i
                         ∫ ° Ads =  ∫  ∇ A V  (B 3.1.1)    S V     V   i
                                   d
                               V
                        S V                          where the dots are to be replaced by a vector field,
                 This is called the Gauss theorem. Due to this   or even a scalar field, while i =  12 … D  . This
                                                                           ,,
                                                                               ,
                 equation the properties of the field inside   -espe-  means that the surface integral is related to the
                                            V
                 cially its sources- are related to its properties at the   volume integral of the derivative of the field.
                 surface – especially its flux.
                Current      This is the current density of probability or simply the current density.
                Density      For a given electronic system its expectation value multiplied by the unit
                             charge corresponds to a measurable electrical current density.



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