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ELECTRIC MOTORS  211



        applies mostly to flammable and combustible liquids,  position of ignition chambers, method and rate of
        although there are certain solids (such as camphor    heating, residence time, and method of flame detec-
        or naphthalene) that slowly evaporate or volatil-     tion. Reported ignition temperatures are affected
        ize at ordinary room temperatures. Also, liquids,     by the test methods employed.
        such as benzene, freeze at relatively high tempera-      Since ignition temperature is the temperature at
        tures and, therefore, have flashpoints while in the   which ignition may occur due to contact with a
        solid state.                                          hot surface, it follows that motor selection must
           The term "propagation of flame" is used to         be based on the maximum surface temperature
        describe the spread of flame from the ignition        that will never exceed the auto-ignition tempera-
        source through a flammable mixture. A gas or          ture of any potentially explosive mixture likely to
        vapor mixed with air in proportions below the         exist. The National Electrical Codes (Table 12-6)
        lower limit of flammability, may burn at the source   indicates the maximum external surface temperature
        of ignition. In other words, they may burn in the     for motors in service with combustible materials.
        zone immediately surrounding the source of igni-         Ignition temperature depends on the type and
        tion, without propagating (spreading away) from the   concentrations of gasses and vapors present. Table
        source of ignition. However, if the mixture is within  12-7 compares the flashpoint and ignition (or auto-
        the flammable range, the flame will spread through-   ignition) temperatures for some common materials.
        out when a source of ignition is supplied. The use
        of the term "flame propagation," therefore, can be
        used to distinguish between combustion that takes
        place only at the source of ignition and that which
        travels (propagates) through the mixture.
           Ignition temperature (or auto-ignition tem-        TABLE 12-6. NEC Maximum External Surface
        perature) of a substance, whether solid, liquid, or   Temperatures
        gaseous, is the minimum temperature required to                                           Ignition
        initiate or cause self-sustained combustion in the                      Maximum         Temperature
        absence of any ignition source, such as a spark or    Temperature        Surface       of Combustible
        flame. To avoid the risk of explosion, the tempera-   Class           Temperature         Material
        ture of any part or surface must always be below      Tl               450°C/842°F      > 450°C/842°F
        the ignition temperature.
           Ignition temperatures observed under one set of    T2               300°C/572°F      > 300°C/572°F
        conditions may alter significantly with changing      T2A              280°C/536°F      > 280°C/536°F
        conditions, such as:                                  T2B              260°C/500°F      > 260°C/500°F
                                                              T2C              230°C/446°F      > 230°C/446°F
           • Percentage composition of the vapor or           T2D              215°C/419°F      > 215°C/419°F
             gas-air mixture
           • Shape or size of the space in which              T3               200°C/392°F      > 200°C/392°F
             ignition occurs                                  T3A              180°C/356°F      > 180°C/356°F
           • Rate and duration of heating                     T3B              165°C/329°F      > 165°C/329°F
           • Reactivity of any other materials present        T3C              160°C/320°F      > 160°C/320°F
                                                              T4               135°C/275°F      > 135°C/275°F
        Thus, ignition temperatures should be viewed          T4A              120°C/248°F      > 120°C/248°F
        as approximations.                                    T5               100°C/212°F      > 100°C/212°F
           There are many differences in ignition tempera-
        ture test methods including size, shape and com-      T6                85°C/185°F      > 85°C/185°F



                     TABLE 12-7. Flashpoint and Auto-ignition Temperature for Some Common Materials
                                                            Auto-ignition                           Explosion
        Gas/Vapor/Liquid             Flashpoint             Temperature             Class            Group
        Acetone                      -20°C/ -4°F             465°C/869°F             Tl                IIA
        Benzyl Alcohol                93°C/200°F             436°C/817°F             T2                IIA
        Benzene                      -11°C/ 12°F             498°C/928°F             Tl                IIA
        Gasoline (petrol)            -43°C/-45°F             280°C/536°F            T2A                IIA
          No. 2 Diesel Fuel                                                                            IIA
        Hydrogen Sulfide                gas                  260°C/500°F            T2B                IIB
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