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158                                                   6 Soil Pollution



               Table 6.1   Acceptable amounts of heavy metals in sewage sludge for agricultural use (Chefetz
            et al.   1996 ; Siuta  1999 ; Moreno et al.  1999 )
                                 Soil fertilization, land reclamation
             Metals             Agricultural exploitation    Nonagricultural exploitation
             Lead (Pb)           500                        1,000
             Cadmium (Cd)         10                          25
             Chromium (Cr)       500                        1,000
             Copper (Cu)         800                        1,200
             Nickel (Ni)         100                         200
             Mercury (Hg)          5                          10
             Zinc (Zn)          2,500                       3,500



            On the other hand, repeated applications of compost from sewage sludge on agricultural

            soil have significant effects on the physical and chemical properties of soil (Reddy
            and Overcash  1981 ; Okereke  1985 ). A considerable amount of research has been
            carried out in Europe in order to evaluate the effects of compost from sewage sludge
            on soil properties (Williams and Goh  1982 ). The acceptable limits of some heavy
            metals in sludge for agricultural use are given in Table  6.1 .
                    It has been shown in some studies that through application of appropriate rates of
            sewage sludge, plant growth and physical properties of soil improve substantially
            and their reusable nutritional values increase (Reed et al.  1991 ). The addition of sewage
            sludge gives a slight increase in Cu content of soils and Zn content of plants, which
            suggests that application of sewage sludge on agricultural lands should be carried
            out without surpassing the toxic limits set by the relevant organizations (Saruhan
            et al.  2010 ). Since sewage sludge contains high concentrations of potentially toxic
            elements such as Zn, Ni, Cd, and Cu, problems may arise when sludge is applied
            to an agricultural soil (Sanchez-Monedore et al.  2004 ; Madyiwa et al.  2002 ) and
            heavy metal accumulation also occurs in the plant tissues.
                Biosolids, the product generated from tertiary treatment of waste activated

            sludge, and composted sludge have been used in agricultural fields of Europe and
            China for about a century. Substantial increase in crop yield due to sewage sludge
            application has been observed. But for heavy metal contamination of soil and public
            outrage, Austria, Switzerland, Sweden, and some other European countries have
            imposed a ban on the use of sewage sludge as a fertilizer.



            6.2.3      Contaminants in Garden Composts


              Contaminants in feedstock can impact the quality, marketability, and use of fi nished
            composts. Overuse and persistence of some insecticides could result in contamination
            of yard waste and compost. Since composting is a biologically mediated process,
            there is a considerable interest in knowing if the intense biological activity during
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