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6.2   Sources of Soil Pollutants                                201



               Table 6.6   Typical background and unsafe soil levels of heavy metals
                           Typical background levels     Unsafe for leafy     Unsafe for gardens
                         for non-contaminated soil   or root vegetables   and children
                                                                           −1
                                                     −1
                              −1
             Heavy metal   (mg kg   )           (mg kg   )       contact (mg kg   )
             Arsenic      3–12                   >50              >200
             Cadmium      0.1–1.0                >10              >50
             Copper       1–50                   >200             >500
             Lead         10–70                  >500             >1,000
             Nickel       0.5–50                 >00              >500
             Selenium     0.1–3.9                >50              >200
             Zinc         9–125                  >200             >500
                Source :    http://www.aleastern.com/forms/Heavy%20Metal%20Interpretation.pdf



               Table 6.7   Threshold levels of heavy metals in soil

                            Threshold levels in soils          Threshold levels in soils
                          of concern for human               of concern for human
                                   −1
                                                                       −1
             Heavy metals   health (mg kg   )    Heavy metals   health (mg kg   )
             Arsenic       0.07                 Molybdenum       380
             Cadmium       1.70                 Nickel         1,600
             Chromium      1,00,000             Selenium         380
             Cobalt        660                  Silver           380
             Copper        3,000                Vanadium         530
             Lead          80                   Zinc          23,000
             Mercury       18
                Source : California Office of Human Health Assessment,    http//:oehha.ca.gov/risk/chhsltable.html





            6.2.12.2   Safe Limits of Heavy Metals in Soil
              The term “safe level” needs to be explained. A level safe for growing vegetables
            may not be safe for children’s contact. A level safe for human may be toxic for
            crops. Moreover, getting a universally accepted safe limit of heavy metals in soil is
            diffi cult. Table  6.6  gives some typical background levels in non-contaminated soils
            of some common heavy metals and their unsafe levels for vegetable growing and
            gardening.
                 Zhou et al. ( 2008 ) proposed that “maximum allowable concentrations” of Cd,
                                                                      − 1
            Cu, and Hg in Chinese agricultural soils are 0.30, 50.00, and 0.30 mg kg   , respec-
            tively. According to Coskun et al. (  2006 ), “world limits” of Cd, Hg, Pb, and As in
                                              − 1
            soil are 0.35, 0.30, 35.00, and 10.00 mg kg   , respectively. The toxic limits in soils
            of As, Cd, Cr, Cu, Pb, Hg, Mo, Ni, Se, and Zn are 1–4, 5–20, 5–30, 20–100, 5–30,
                                                    − 1
            1–3, 10–100, 30–300, 5–10, and 100–400 mg kg   , respectively (Alloway  1995 ).
            Threshold levels of heavy metals in soils of concern for human health are given in
            Table  6.7 .
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