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6.2 Sources of Soil Pollutants 201
Table 6.6 Typical background and unsafe soil levels of heavy metals
Typical background levels Unsafe for leafy Unsafe for gardens
for non-contaminated soil or root vegetables and children
−1
−1
−1
Heavy metal (mg kg ) (mg kg ) contact (mg kg )
Arsenic 3–12 >50 >200
Cadmium 0.1–1.0 >10 >50
Copper 1–50 >200 >500
Lead 10–70 >500 >1,000
Nickel 0.5–50 >00 >500
Selenium 0.1–3.9 >50 >200
Zinc 9–125 >200 >500
Source : http://www.aleastern.com/forms/Heavy%20Metal%20Interpretation.pdf
Table 6.7 Threshold levels of heavy metals in soil
Threshold levels in soils Threshold levels in soils
of concern for human of concern for human
−1
−1
Heavy metals health (mg kg ) Heavy metals health (mg kg )
Arsenic 0.07 Molybdenum 380
Cadmium 1.70 Nickel 1,600
Chromium 1,00,000 Selenium 380
Cobalt 660 Silver 380
Copper 3,000 Vanadium 530
Lead 80 Zinc 23,000
Mercury 18
Source : California Office of Human Health Assessment, http//:oehha.ca.gov/risk/chhsltable.html
6.2.12.2 Safe Limits of Heavy Metals in Soil
The term “safe level” needs to be explained. A level safe for growing vegetables
may not be safe for children’s contact. A level safe for human may be toxic for
crops. Moreover, getting a universally accepted safe limit of heavy metals in soil is
diffi cult. Table 6.6 gives some typical background levels in non-contaminated soils
of some common heavy metals and their unsafe levels for vegetable growing and
gardening.
Zhou et al. ( 2008 ) proposed that “maximum allowable concentrations” of Cd,
− 1
Cu, and Hg in Chinese agricultural soils are 0.30, 50.00, and 0.30 mg kg , respec-
tively. According to Coskun et al. ( 2006 ), “world limits” of Cd, Hg, Pb, and As in
− 1
soil are 0.35, 0.30, 35.00, and 10.00 mg kg , respectively. The toxic limits in soils
of As, Cd, Cr, Cu, Pb, Hg, Mo, Ni, Se, and Zn are 1–4, 5–20, 5–30, 20–100, 5–30,
− 1
1–3, 10–100, 30–300, 5–10, and 100–400 mg kg , respectively (Alloway 1995 ).
Threshold levels of heavy metals in soils of concern for human health are given in
Table 6.7 .