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6.2   Sources of Soil Pollutants                                209



               Table 6.10   Toxicities of heavy metals to human
              Heavy metals     Common toxicities of heavy metals in human
                 a
             Arsenic        Arsenicosis is the most common disease caused by drinking
                            As-contaminated water for a long time. Inorganic arsenic compounds are
                            “known to be human carcinogens.” Arsenic may cause cancers of the
                            bladder, kidney, skin, liver, lung, colon, and lymph. Darkening of the
                            skin and the appearance of small “corns” or “warts” on the palms, soles,
                            and torso
                  a
             Cadmium        The well known itai-itai disease was caused by the consumption of rice
                            grown by irrigating with Cd-contaminated river water in Japan after
                            1945. Cd toxicity causes renal tubular dysfunction, high blood pressure,
                            lung damage, and lung cancer. Acute Cd inhalation may lead to
                            pneumonitis and pulmonary edema. Chronic exposure via inhalation may
                            cause emphysema. One of the most widely known toxic effects
                            manifested by Cd poisoning is nephrotoxicity
             Chromium   b      Impaired growth, altered immune function, disturbances in aortic plaque and
                            size, corneal lesion formation, and decrease in reproductive functions;
                            both Cr(III) and Cr(VI) are potent human carcinogens. The major target
                            organ for Cr(III) and Cr(VI) is the respiratory tract. Classical symptoms
                            are perforations and ulcerations of the septum, bronchitis, decreased
                            pulmonary function, and pneumonia
                 b
             Copper         Copper is an essential element. Cu toxicity in humans is very rare and is
                            usually associated with long-term intake of cow’s milk or with severe
                            malnutrition in infants and young children
             Lead   a       Lead damages the central nervous system, kidneys, and lungs. It causes

                            anemia; nausea, anorexia,   and abdominal cramps; muscle aches and joint

                            pain; difficulty in breathing, asthma, bronchitis, and pneumonia; and
                            damage to the fetus and miscarriage. Children are more vulnerable to Pb
                            poisoning than adults. Pb may cause male infertility
                  a
             Mercury        Severe mercury poisoning occurred in Minamata of Japan from
                             contaminated fish and in Iraq from contaminated wheat. Wheat was

                            sprayed with MeHg fungicide. In the outbreak more than 6,000 children
                            and adults had been poisoned, with nearly 500 deaths. Symptoms include
                            paresthesia, ataxia, dysarthria, and deafness. Chronic Hg poisoning may
                            result from exposure to small amounts of Hg over long periods;
                            symptoms include salivation, loss of appetite, anemia, gingivitis,
                            excessive irritation of tissues, nutritional disturbances, and renal damage
                            accompanied by proteinuria. Exposure to Hg may cause nausea, severe
                            gastrointestinal irritation, and abdominal pain
             Molybdenum   b      Toxic effects of Mo include increased blood xanthine oxidase, increased
                            concentrations of uric acid in blood and urine, and a high incidence of
                            gout
                a
             Nickel         Exposure to nickel sulfate and nickel chloride can cause vomiting and
                            headaches and the metal can cross human placental barrier, affecting the
                            fetus. Ni-sensitive individuals often develop contact dermatitis.
                            Inhalation of Ni compounds has been considered responsible for lung,
                            sinonasal, and laryngeal carcinomas. Other illnesses include
                              pneumonoconiosis and emphysema. Ni may cause kidney cancer.
                            Among different types of Ni compounds, crystalline nickel subsulfi de is
                            carcinogenic, whereas amorphous NiS is not
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