Page 85 - Standard Handbook Petroleum Natural Gas Engineering VOLUME2
P. 85

Basic  Principles, Definitions, and Data   73


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                                                            El  HYDROGEN
                                                            El HYDROGEN
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                                                            0 NITROGEN
                                                               NITROGEN
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                                                            A  CARBON   DIOXIDE
                                                            A CARBON  DIOXIDE
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                               RECIPROCAL  MEAN  PRESSURE,  (atrn)"
                                  Figure 5-50. Gas slippage in  core [128].
                  shows the variation in permeability as a function of  mean pressure for hydrogen,
                  nitrogen, and carbon dioxide. Klinkenberg found that by  extrapolating all data
                  to  infinite  mean  pressure, the  points  converged at  an  equivalent liquid per-
                  meability (kJ,  which was  the  same as the permeability of  the porous medium
                  to a nonreactive single-phase liquid. From plots of this type, Klinkenberg showed
                  that the equivalent liquid permeability could be obtained from the slope of  the
                  data, m,  the measured gas permeability, kg, at a mean flowing pressure  ji, at
                  which  k,  was  observed
                            k         m
                     k,  =                                                       (5-77)
                         l+&)  = kc-=
                                       P
                  where b  is  a  constant for  a  given  gas  in  a  given medium  and is  equal to  m
                  divided by  kp. The amount of correction, known as the Klinkenberg effect, varies
                  with permeability and is more significant in low  permeability formations.
                    In  recent  studies  [ 129,1301 with  very  low  permeability  sandstones, liquid
                  permeabilities were  found to be  less than  gas permeabilities at  infinite mean
                  pressure, which is in contrast with the prior results of Klinkenberg. Furthermore,
                  it  has been  shown  [ 1301  that  liquid permeabilities decreased with  increasing
                  polarity of the liquid, For gas flow or brine flow in low-permeability sandstones,
                  permeabilities  were  independent  of  temperature  at  all  levels  of  confining
                  pressure [130]. The data [l30] showed that for a given permeability core sample
                  at  a  given  confining pressure, the Klinkenberg slip factors and  slopes of  the
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