Page 315 - Tandem Techniques
P. 315

Page 299

































                                                          Figure 8.6
                                                  Different Types of Nebulizers
            The nebulizer was arranged to deposit the solutes on a rotating disk as shown in Figure 8.7. The outer
            sheath of gas communicates momentum to the liquid center and the stream is broken up into droplets.
            The heating causes rapid evaporation and the solid material is directed to a very small circular spot on
            the surface of the stage. It was shown that this nebulizing procedure provided narrow discrete spots of
            solute, and could be used satisfactorily with aqueous solvent mixtures. In similar systems, the transport
            medium consisted of a layer of potassium chloride on the surface of a zinc-selenium metallic stage, and
            the IR spectrum of the deposited material, obtained by diffuse transmission spectrometry. However, it
            was not possible to use potassium chloride with aqueous solvents. The authors used a zinc-selenium
            window as the transport material, and then examined the spots after deposition, using an FTIR
            microscope to measure the transmission spectra.
   310   311   312   313   314   315   316   317   318   319   320