Page 207 - Thermodynamics of Biochemical Reactions

BasicBiochemData2 207

Clear[acetaldehydeis, acetateis, acetoneis, acetylcoAis, acetylphosis,
aconitatecisis, adenineis, adenosineis, adpis, alanineis, ammoniais, ampis,
arabinoseis, asparaginelis, aspartateis, atpis, bpgis, butanolnis, butyrateis,
citrateis, citrateisois, coAis, colglutathioneis, coagis, coatotis, coaqis,
cogis, creatineis, creatinineis, cysteinelis, cystinelis, cytochrmecoxis,
cytochromecredis, dihydroxyacetonephosis, ethanolis, ethylacetateis, fadoxis,
fadredis, fadenzoxis, fadenzredis, ferredoxinoxis, ferredoxinredis, fxnnoxis,
fmnredis, formateis, fructoseis, fructose6phosis, fumaratel6phosis. fumarateis,
galactoseis, galactoselphosis, glucoseis, glucoselphosis, glucose6phosis,
glutamateis, glutamineis, glutathioneoxis, glutathioneredis, glyceraldehydeis,
glycerolis, glycerol3phosis, glycineis, glycolateis, glycylglycineis, glyoxylateis,
haaqis, hagis, hlois, h202agis. hydroxypropionatebis, hygoxanthineis, indoleis,
ketoglutarateis, lactateis, lactoseis, leucineisolis, leucinelis, lyxoseis,
malateis, maltoseis, mannitolDis, mannoseis, methaneaqis, methanegis, methanolis,
methioninelis, methylamineionis, n2aqis. n2gis, nadoxis, nadredis, nadpoxis,
nadpredis, oaaqis, oagis, oxalateis, oxaloacetateis, oxalosuccinateis, palmitateis,
pepis, pgais, pg3is, phenylalanineLis, piis, ppiis, propanolais, propanolnis,
pyruvateis, retinalis, retinolis, riboseis, riboselphosis, ribose5phosis,
ribuloseis, serinelis, sorboseis, succinateis, succinylcoAis, sucroseis,
thioredoxinoxis, thioredoxinredis, tryptophanelis, tyrosinelis, ubiguinoneoxis,
ubiquinoneredis, urateis, ureais, uricacidis, valineLis, xyloseis, xyluloseis];
Evaluate[listdG31] = Map[calcdG31, listfnpHis] ;

ace tonei s
I80.0378, 83.7102, 84.8958)

This is a list of the names of reactants.
1 i s t = { acetaldehyde ,I , ace t a t e , I' acetone *I , *I ace t y 1 coA , ace t yl pho s , aconi tat ec i s ,
'I
"adenine", "adenosine", nadpaa, "alanine", "ammonia", ll~p*, "arabinose".
"asparagineL", "aspartateal, tlatpll, ltbpgml, "butanoln", "butyrate", "citrate",
"citrateiso", I1coAn, "coAglutathione", llc02g~~, "co2totl1, I1coaqnl, licogii, "creatine",
"creatinine", "cysteineL", f'cystineL1l, mmcytochromecoxll, "cytochromecred",
"dihydroxyacetonephos", "ethanol", 'ethylacetate", "fadox", "fadr~d~~, "fadenzox",
" f adeazredlf, I'f erredoxinox" , llferredoxinredll, fmnoxll, llfmnredml, f ormate 'I,
I1
"fructoseB1, 11fructose6phos "f ru~tosel6phos~~, "fumaratetV, "galactose1',
'I,
"galactoselphos", I1glucosenl, "glUCOSelphOS", 11g1~~ose6ph~s11, "glutamatell,
llglutaminell, "glutathioneox", "glutathionered", "glyceraldehydephosll, llglycerolll,
"glycerol3~hos", ''glycine", llglycolate*l, "glycylglycine", "glyoxylatetl,
11h2ag11, "h2gIt, "h20", 11h202ag11, "hydroxypropionatebll, "hypoxanthineSf, "indole",
" ke t og lu t ara t e *I , 1 act ate It , 1 act o s e I' , 1 euc i ne i soL " , 1 euc i neL *I , 1 yxo s e ,
1'
1'
11
"malatell, "maltose", %annitolD", 11mannose18, "methaneaq', "methaneg", iimethanol",
"methionineL', "methylamineion", lmn2aq11, s1n2glm, "nadox", "nadred" , "nadpox",
"nadpred", 1102a~11, 1102g11, "oxalatelq, "oxaloacetate", lroxalosuccinatelm, llpalmitatel*,
"pep"r "pg2", "pg3", llphenylalanineL1l, lmpill, llppill, "propanol2", llpropanolnll.
"retinal", "ribose". "riboselphosn, 1nribose5phos1i,
"pyruvate'*, "retinall~,
"ribulose", "serineL", lwsorboselv, "succinate'l, "succinylcoAwl, ilsucrosell,
"thioredoxinox" , "thioredoxinredl', 'ltryptophaneLml, "tyrosineL1*, ~gubiquinoneox",
"ubiquinonered1*. "urate" , lgurea", "uricacid" , "valineL", "xylose", iixyluloseii } ;
Table 1 Standard Transformed Gibbs Energies of Formation in kJ mol-' at 298.15 K, pH 7, and Ionic Strengths of 0, 0.10,
and 0.25 M

=
tablel=PaddedForm[TableForm[listdG3I,TableHead~ngs-~{list, {"I = 0 M1m,llI 0.10 M","I =
0.25 M**)},TableSpacing->{.3,3)1,18,2)1