Page 260 - Bird R.B. Transport phenomena
P. 260

244   Chapter 8  Polymeric Liquids


       EXAMPLE   8.3-3      Rework Example 3.6-3 for a power law  fluid.
      Tangential Annular    SOLUTION
            f
         ,^ J               Equations 3.6-20 and  3.6-22 remain unchanged  for  a non-Newtonian fluid,  but  in lieu  of Eq.
      r1  4 5 4
      Fluid '               3.6-21 we  write  the  ^-component of  the  equation  of  motion in  terms  of  the  shear  stress  by
                            using Table B.5:
                                                          0=  -\4-(r r )                        (8.3-15)
                                                                   2
                                                                    r0
                                                               r 2  dr
                            For the postulated velocity  profile, we get for the power law  model (with the help of Table B.I)
                                                     _  -  ...  d  (

                                                                    n
                                                            (  d  he\\ ~ l  d  ho

                                                                                                (8.3-16)

                            Combining Eqs. 8.3-15 and  16 we  get

                                                                                                (8.3-17)

                            Integration gives

                                                                                                (8.3-18)

                            Dividing by  r 2  and taking the nth root gives a first-order  differential  equation for  the angular
                            velocity
                                                          л  / 7 1  \  -i  (C  \\ln
                                                                                                (8.3-19)
                                                         dr\rj     r\ 2
                                                                     r  /
                            This may be integrated with the boundary conditions in Eqs. 3.6-27 and 28 to give
                                                          v   1 -  ( R/r) 2/n
                                                           e        K                           (8.3-20)
                                                             _       2/п
                                                         Ц/  "   1 -  к
                            The (z-component of the) torque needed on the outer cylinder to maintain the motion is then



                                                                       2TTRL  • R               (8.3-21)
                            Combining Eqs. 8.3-20 and 21 then gives
                                                                      (2/n)
                                                     T  =                                       (8.3-22)
                                                       7
                            The Newtonian result can be recovered by setting n = 1 and m = /JL. Equation 8.3-22 can be used
                            along with torque versus  angular velocity data to determine the power law parameters m and n.


       §8.4  ELASTICITY AND THE LINEAR VISCOELASTIC MODELS

                            Just after  Eq.  1.2-3, in the discussion about generalizing Newton's  "law  of  viscosity/'  we
                            specifically  excluded  time  derivatives  and  time  integrals  in  the  construction  of  a  linear
                            expression  for  the  stress  tensor  in  terms  of  the  velocity  gradients.  In  this  section,  we
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