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5

                                 Diamond thin films: a twenty-first century
                                    material


                                    Paul W. May

                                    School of Chemistry, University of Bristol, Bristol BS8 1TS, UK










                                 Diamond has some of the most extreme physical properties of any
                                 material, yet its practical use in science or engineering has been limited
                                 due its scarcity and expense. With the recent development of techniques
                                 for depositing thin films of diamond on a variety of substrate materials, we
                                 now have the ability to exploit these superlative properties in many new
                                 and exciting applications. In this paper, we shall explain the basic science
                                 and technology underlying the chemical vapour deposition of diamond
                                 thin films, and show how this is leading to the development of diamond as
                                 a twenty-first century engineering material.


                                 5.1 The diamond in history

                                 Probably more so than any other gemstone, diamonds feature more pre-
                                 dominantly in the history and cultural heritage of the human race. They
                                 were prized for their scarcity for centuries, and still remain a symbol of
                                 wealth and prestige to this day. The word diamond comes from the Greek
                                 adamas, meaning indestructible. Diamonds were first mined in India over
                                 4000 years ago, but the modern diamond era only began in 1866, when huge
                                 diamond deposits were discovered in Kimberley, South Africa, creating a
                                 huge rush of European prospectors. The wealth this created helped to
                                 underwrite the British Empire, and changed the fates of many African
                                 countries.
                                    Apart from their appeal as gemstones, diamonds possess a remarkable


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