Page 78 - A Practical Introduction to Optical Mineralogy
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SILICATE  MINERALS                                                         FELDSPAR  GROUP
            Epidote (pistacite)   Ca 2Fe' • A1 2 (0H)Si,0, 2       monoclinic             I  II Kl ERENCE  A section perpendicular to the c axis will  give a biaxial negative figure
                                                      1.591 : 1: 1.812, .B  = 115°24'         HGURE   with a large 2V; thus an optic axis figure is preferable when determining
                                                                                                   the sign.
                                                      ~                                  1111  M II'.ATU RES  Lamellar twinning  may sometimes be present.
                                                                                          1111  IIKRENCE  Epidote  is  an  important  mineral  in  low  grade  regional  metamorphic
                                                      II
                                                      II                                           rocks, where it marks the beginning of the epidote-amphibolite facies,
                                                     /I
                                                a   I   I                                          forming from the breakdown of chlorite. Epidote also forms from sauss-
                                                I   I   I                                          uritisation  of  plagioclase  feldspar  and  from  the  breakdown  of
                                                1  1   I
                                                1  I   I                                           amphiboles in basic igneous rocks, these changes being due to late stage
                                                 I   I
                                                I  I   I                                           hydrothermal alteration. In  highly amphibolitised basic igneous rocks,
                                                V   I
                                               II   I                                              clusters of epidote crystals are commonly seen associated with plagio-
                                                                                                   clase feldspar and often within  amphibole  minerals.
                                                                                                   Feldspar group                          Tektosilicates
                                                               ---- b =  13                        Introduction
                                                                                                   The feldspars are the most important minerals in  rocks. They occur in
                                                                                                   igneous, metamorphic and sedimentary rocks, and their range of com-
                                                                                                   position  has  led  to  their  use  as  a  means  of classifying  igneous  rocks.
                                                                                                   Feldspars  are  absent  only  from  certain  ultramafic  and  ultra-alkaline
                                                                                                   igneous  rock  types  and  carbonatites.  Feldspars  occur  in  almost  all
                                       I
                                       I                                                           metamorphic  rocks,  being  absent  only  from  some  low  grade  pelitic
                                      I
                                     a                                                             types, pure marbles and pure quartzites. In sedimentary rocks feldspars
                                                                                                   are  common  constituents  of  many  arenaceous  rocks,  but  are  less
                                                                                                   common in shales (clay rocks) and mudstones. Feldspars are difficult to
                       n.  =  1.715  }                                                             detect  (although  XRD  investigation  would  reveal  their  presence)
                       n p  =  1.725   Rls increase with  increasing Fe'• content
                       ny =  1.734                                                                 because of the  minute grain  size  ( < 0.002 mm)  of these  argillaceous
                                                                                                   rocks.
                       a  =  0.019-0.049 (variable with  composition)
                                                                                                     Although the most ubiquitous of minerals, feldspars have a restricted
                       2V.  =  variable  64°-90° -ve
                                                                                                   range of composition. There are two  main types of feldspars:
                       OAP is  parallel to (010)
                       D  =  3.38-3.49   H  = 6
                                                                                                   (a)  Alkali feldspars,  which  range  between the end members ortho-
                  coLOUR  Colourless to  pale yellowish  green.                                        clase KAISi,0 8  and albite NaAISi 3 0 8 •
             *PLEOCHROISM  Slightly pleochroic with a colourless to pale yellowish green, ,B greenish   (b)  Plagioclase  feldspars,  which  range  between  the  end  members
                       and y  yellowish.                                                               albite NaAISi 3 0 8  and anorthite CaAI 2 Si 2 0 8 •
                   HABIT  Found  in  aggregates  of  elongate  prismatic  crystals  with  pseudo
                       hexagonal cross sections.                                                    From this it is obvious that albite is common to both feldspar types, and
                CLEAVAGE  {001}  perfect (similar to clinozoisite).                                the  most  usual  way  of depicting  the  complete feldspar  group  is  in  a
                 *RELIEF  High.                                                                    ternary  (or triangular)  diagram  with  orthoclase,  albite  and  anorthite
               ALTERATION  None.                                                                   representing the composition of each apex (Fig. 2.7). This reveals that
            *BIREFRINGENCE  Moderate  to  high,  showing  low  second  order  to  upper  third  order   the alkali feldspars can contain up to 10% anorthite molecule in their
                       colours.  Some sections may show low anomalous interference colours         structure,  and  similarly  plagioclase  feldspars  can  contain  up  to  10%
                       similar to clinozoisite.                                                    orthoclase molecule in their structure.
               EXTINCTION  Oblique to  cleavage in  pseudo-hexagonal sections (see figure), other·   The optical  properties and structure of the feldspars  depend  upon
                       wise straight  on cleavage in  prismatic section.                            their temperature of crystallisation and their cooling history. Thus for
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