Page 80 - A Practical Introduction to Optical Mineralogy
P. 80

SILICATE  MINERALS

               Figure 2.7                         Or                                     II  1111• 2.8                         An
               Feldspar                                                                  Ill •h
               composition                                                                trlprlnture
               diagram.
                                                                                          "'""''·



                                                                                                            high labradorite
                                                                                                                             TWO FELDSPARS





                                                                                                      high oligoclase     /
                                                                                                                         /
                                                                                                                        /
                                                                                                                       /
                                                                                                                     .....
                                                                                                                   ..... ..... K-high  albite
                                                                                                                    (- monalbite)
                              Ab                                      An
                          example in  quickly cooled extrusive igneous rocks, the potassium fcld
                          spar that forms  has a tabular crystal habit and is  called sanidine, with
                          optical  properties  peculiar  to  that  mineral.  However,  when  plutonu
                          igneous rocks crystallise, their cooling rate is  much slower, which cou
                                                                                                                               An
                          trois the kinetics of order-disorder in the feldspar structure, lead in • to                            primitive
                          the formation of orthoclase, with a prismatic habit and slightly differ  ·nt                            anorthite
                          optical properties from  those of sanidine.
                            Much work has been carried out on the feldspar  minerals in  rcc ·ut
                          years, and Smith (1974) summarised the differences between the diff ·r
                          ent feldspar types. Figures 2.8, 2.9 and 2.10 illustrate the compositiou
                          and nomenclature of the feldspars at various temperatures. The  t  1 111
                          ' temperatures'  refers to the temperatures at which effective structtuul
                          re-equilibration ceases, and the mineral structure will not be subje  t 1!1
                          any  change  thereafter.  It is  a  time-temperature-kinetic relationshrp
                          The feldspars  are  divided  into  three groups - high  (representing  •
                          trusive  rocks), intermediate (representing hypabyssal  rocks and  smull
                           intrusions)  and  low  (deep  seated  plutonic  rocks  and  metamorphn
                           rocks).
                            Figure 2.8  shows  feldspars  quenched  from  high  temperature.  /\11
                          arbitrary  boundary  from  albite  (Ab)  with  anorthite  (An)  equal  Itt                                      low sanidine
                          orthoclase  (Or)  defines  the  alkali  feldspar  and  plagioclase  feldspnr                            perthites   (orthoclase)
                          fields. The plagioclase feldspars are divided into six divisions at 1 0,  JO,   low  albite·~~~~::,.__::~:::,_::::,__;:,._...o.___,__...o.___,__...o.___,____,____,_...o._.::-...., ..... ..o~.
                                                                                                           Ab                                       Or
                           50, 70 and 90 mol per cent An, and the feldspars in these divisions ll ll'
                           named on the diagram as (high) albite0-10% An, oligoclase 10-30% /\11,
                           andesine,  labradorite,  bytownite  and  anorthite  90-100%  An.  In  th •
                           alkali feldspars, the boundary at 40% Or between high albite and  hi  •h
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