Page 81 - A Practical Introduction to Optical Mineralogy
P. 81

SILICATE  MINERALS

 Figure 2.7   Or   II  1111• 2.8               An
 Feldspar   Ill •h
 composition   trlprlnture
 diagram.
          "'""''·



                           high labradorite
                                            TWO FELDSPARS





                     high oligoclase      /
                                         /
                                        /
                                      /
                                     .....
                                   ..... ..... K-high  albite
                                    (- monalbite)
 Ab   An
 example in  quickly cooled extrusive igneous rocks, the potassium fcld
 spar that forms  has a tabular crystal habit and is  called sanidine, with
 optical  properties  peculiar  to  that  mineral.  However,  when  plutonu
 igneous rocks crystallise, their cooling rate is  much slower, which cou
                                               An
 trois the kinetics of order-disorder in the feldspar structure, lead in • to   primitive
 the formation of orthoclase, with a prismatic habit and slightly differ  ·nt   anorthite
 optical properties from  those of sanidine.
 Much work has been carried out on the feldspar  minerals in  rcc ·ut
 years, and Smith (1974) summarised the differences between the diff ·r
 ent feldspar types. Figures 2.8, 2.9 and 2.10 illustrate the compositiou
 and nomenclature of the feldspars at various temperatures. The  t  1 111
 ' temperatures'  refers to the temperatures at which effective structtuul
 re-equilibration ceases, and the mineral structure will not be subje  t 1!1
 any  change  thereafter.  It is  a  time-temperature-kinetic relationshrp
 The feldspars  are  divided  into  three groups - high  (representing  •
 trusive  rocks), intermediate (representing hypabyssal  rocks and  smull
 intrusions)  and  low  (deep  seated  plutonic  rocks  and  metamorphn
 rocks).
 Figure 2.8  shows  feldspars  quenched  from  high  temperature.  /\11
 arbitrary  boundary  from  albite  (Ab)  with  anorthite  (An)  equal  Itt   low sanidine
 orthoclase  (Or)  defines  the  alkali  feldspar  and  plagioclase  feldspnr   perthites   (orthoclase)
 fields. The plagioclase feldspars are divided into six divisions at 1 0,  JO,   low  albite·~~~~::,.__::~:::,_::::,__;:,._...o.___,__...o.___,__...o.___,____,____,_...o._.::-...., ..... ..o~.
                           Ab                                       Or
 50, 70 and 90 mol per cent An, and the feldspars in these divisions ll ll'
 named on the diagram as (high) albite0-10% An, oligoclase 10-30% /\11,
 andesine,  labradorite,  bytownite  and  anorthite  90-100%  An.  In  th •
 alkali feldspars, the boundary at 40% Or between high albite and  hi  •h
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