Page 315 - Adsorption by Powders and Porous Solids
P. 315

ADSORPTION BY POWDERS AND POROUS SOLIDS





















































   Figure 10.8.  Nitrogen isotherms (top) and a,-plots (bottom) for mesoporous silica gels A,  J and G
   (from Bhambhani et al., 1972).

     As explained in Chapter 8, the extemal surface area, a(ext, S), available for multi-
   layer adsorption can be calculated from the highp/pO section of an a,-plot,  provided
   that there is an adequate range of linearity to confii the absence of  capillary con-
   densation. This condition is clearly fulfilled with gels D and E, and their external
   areas are therefore recorded in Table 10.8.
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