Page 148 - Adsorption Technology & Design, Elsevier (1998)
P. 148

Design procedures  137







                                                 g










                                                                Y
                                                              Vm 3
                   Vm  a
                   Co kg/m 3                                  cf kg/m 3



                                            i                ~



                                              M  kg
                                              q  kg/kg




            Figure 6.1  Single-stage contacting of a batch of fluid with a batch of adsorbent.


            The adsorbent is initially free from the impurity. The isotherm is linear (that
            is, it follows Henry's law as described in Section 3.3.2) and is given by"

                                                                         (6.1)
              q = Kc
            where q is the loading of the impurity on the GAC  (kg impurity/kg GAC) in
            equilibrium  with the impurity concentration  in the water, c (kg/m3), and K is
            the equilibrium  constant  (m3/kg).
              It  is  assumed  that  water  is  not  adsorbed  and  since  the  impurity
            concentration  is  always  low,  the  volume  of solution  does  not  change.  The
            mass balance on the impurity is therefore  as follows:
              V (co -  cf) = Mq                                          (6.2)

            If  the  adsorbent  were  not  initially  free  from  the  impurity  but  had  been
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