Page 152 - Adsorption Technology & Design, Elsevier (1998)
P. 152

140  Design procedures













            Vm 3                           Vm 3           2      ~   Vm 3
            Co kg/m 3                      c~ kg/m 3
                                                                     cf  kg/m 3


                            ~r  M, kg
                            I  ql  kg/kg
                                                          1'  q2 kg/kg
            Figure  6.3  Stagewise contacting of a batch of fluid with three batches of adsorbent.



              Simultaneous  solution  of the impurity mass balance with the equilibrium
            relationship for the first batch vessel yields M1"

                            )
              M1 = ~    -- 1                                            (6.7)

            The  loading  ql  is  in  equilibrium  with  the  intermediate  concentration  cl.
            Simultaneous  solution  of the  impurity  mass  balance  with  the  equilibrium
            relationship for the second batch vessel yields M2:


              /142-~     -- 1                                            (6.8)


            For the total mass of adsorbent  to be a minimum,  the differential  of (M1  +
            M2)  with  respect  to  the  intermediate  concentration  cl  needs  to  be  zero.
            Hence, it can be shown that:
              cl =  (c0.cf) ~                                           (6.9)

            Substitution  of cl  from  equation  (6.9)  into  equations  (6.7)  and  (6.8) shows
            that the minimum amount of adsorbent for this purification is given when:

                        [V(c~176 -- 1                                  (6.1 O)
              M1 = M2 = [K~ cf ]
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