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                    178                             3. Heterogeneous Processes and Reactor  Analysis



                                                 u    d   1.167  
                                                  sG G pe      0.9

                                                              

                                                                w
                                                   G   0.767   
               (3.398)
                                                             
                                                     d
                                                 u   sL  L pe       
 
                                                                L
                                                    
  L      
                    with   µ being the dynamic viscosity of w ater and     / Z is in dyn/cm  3  . To convert to N/m,
                                                              P
                         w
                    multiply by 10 (1 dyn     cm/s 1 g  2    10    5  N). In these equations, CGS units should be used.
                    s Liquid holdup in trickle bed r eactor
                    Although liquid holdup is mainly affected by the liquid flow rate, the shape, size, and wet-
                    ting characteristics of the particles, the gas flo and the initial distribution of the liq- w rate,
                    uid are also factored. One of the simpler correlations is that of Midoux   et al  . (Perry and
                    Green, 1999):
                                                h      0.66  X  0.81
                                                 e,t                                  (3.399)
                                                     1 0.66    X  0.81


                    where   h  is the total liquid holdup based on the   total  volume of the empty bed (m  3  /m  3  ).
                           e,t
                    This relationship is valid for 0.1     X   80.
                      The correlation of Sato takes into account the wall effects (Ramachandran and
                    Chaudhari, 1984):


                                               h
                                                e,t  0.185      1 3   X  0.22         (3.400)
                                                          u,m

                                                        6(1  )
                                                  a                                   (3.401)
                                                   u,m
                                                         d
                                                          p,m
                                                          d  p
                                                d  p,m      d 4
                                                     1       p                        (3.402)
                                                         D 6(1  )

                    where   D is the bed diameter in cm. In this equation CGS units should be used.
                    Pironti   et al  v . (1999) deried the following correlation for high   Re  numbers:

                                              h  e,d    0.048  Re  0.403  L,m  Re    0.077  (3.403)
                                                                G,m
                    where
                                                11    Re  L,m  90.4
                                                 9   Re  G,m  110
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