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                    24                                                1. Air and  ater Pollution W


                                                    Table 1.11

                          The releases of the main air pollutants from the industrial sector in Europe (2001)
                    Compound            t/yr         Main source (% contrib ution)
                    Carbon dioxide   955              10  6    Combustion installations (64.9%)
                    Sulfur oxides      2.9           10  6     Combustion installations (68.3%)
                    Carbon monoxide  2.8             10  6     Metal industry (71.2%)
                    Nitrogen oxides  1.5             10  6     Combustion installations (58.3%)
                    Methane               1.4        10  6     Installations for the disposal of
                                                                 nonhazardous waste and landf ills
                                                                 (89.8%)
                    Volatile organic compounds  0.2     10  6  Mineral oil and gas refineries (39.2%)
                    Ammonia              85          10  3     Installations for poultry, pigs,
                                                                 or sows (76.6%)
                    Particulate matter  77           10  3     Combustion installations (47.9%)
                    Nitrous oxide     54             10  3     Basic inorganic chemicals or fertilizers
                                                                 (39.5%)
                    Fluorine              6.4        10  3     Combustion installations (53.3%)
                    Benzene               2         10  3      Mineral oil and gas refineries (52.1%)
                    Polyaromatic hydrocarbons  85.2  Installations for surface treatment or
                                                                 products using organic solv ents
                                                                 (32.9%)
                    Mercury               7.4          Combustion installations (31%)


                      The major amount of water in the chemical industry does not come from chemi- aste
                      w
                    cal reaction steps, but from the subsequent physicochemical processing of the final reac-
                    tion mixture. The most important pollutants of water are the follo wing.


                    •  H N      ,N O      ,N O      ,P O  3   ions
                          4    3     2   4
                    Description  : These ions enter the en Their presence is due to  vironment in the form of salts.
                    xtensi the eve use of fertilizers as a result of the intensification of agriculture. As they are
                    y can lead to eutrophication—the enrichment of water by nutrients,  plant nutrients, the caus-
                    ing an accelerated growth of algae and higher forms of plant life, leading to an undesirable
                    disturbance in the balance of organisms present in the water and in the quality of the water.
                      Source  : Agriculture is the main source, whereas the basic inorganic chemicals and fer-
                    tilizer production activities are responsible for 29 and 25% of the total direct industrial
                    releases of nitrogen and phosphorus, respecti into w , ely v  ater .
                      Impact:  Eutrophication, drinking water quality deterioration.
                    •  Heavy metals
                    Description  : Heavy metals are generally considered to be those whose density e xceeds
                    5 g/cm  3  . Characteristic examples of heavy metals are cadmium (Cd), mercury (Hg), and
                    lead (Pb) (Green   et al  aste- ., 2003). Cadmium is found in the en vironment due to general w
                           ,
                    disposal and industrial activities, including the mining industry metal industry ,
                    coating/electroplating industry, production and deposition of batteries, burning of fossil
                    fuels, the use of phosphate fertilizers, wleaching from wetc. aste incineration, aste deposits,
                    Mercury is found in the environment due to its use in v e.g. batteries and arious products,
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