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108    CHAPTER 5 RATIONAL EFFICIENCY OF POWER PLANT




                Work done by turbine,
                                 w T ¼ h 4   h 6 ¼ 2799   2200:8 ¼ 598:2kJ=kg K:

                                                 w net  w T þ w P  598:2   2:0
                                             th
                Thermal efficiency of the cycle is h ¼  ¼       ¼            ¼ 0:243
                                                  q in  h 4   h 2  2799   342:0
                The maximum net work available can be evaluated from the change of exergy between state
             points 4 and 2. Hence,
                                                b w net ¼ b 4   b 2 :
                It is necessary to define a dead-state condition. This is arbitrary, and in this case will be taken as the
             condition at 1. Hence, p 0 ¼ 0.5 bar; T 0 ¼ 81.3 þ 273 ¼ 354.3 K.
                Thus,
                    b 4 ¼ h 4   T 0 s 4  ðh 0   T 0 s 0 Þ¼ 2799   354:3   6:340   a 0 ¼ 552:7   a 0 kJ=kg;
                    b 2 ¼ h 2   T 0 s 2  ðh 0   T 0 s 0 Þ¼ 342:0   354:3   1:091   a 0 ¼ 44:5   a 0 kJ=kg:
                Hence,
                                      b w net ¼ 552:7  ð 44:5Þ¼ 597:2kJ=kg:
                Thus, the rational efficiency is

                                          w net   w net  598:2   2:0
                                     R
                                    h ¼         ¼     ¼           ¼ 1:00:
                                         b 4   b 2  b w net  597:2
                In this case the rational efficiency is equal to unity because the turbine and feed pump have
             isentropic efficiencies of 100%, and it was assumed that the temperature of the working fluid in the
             condenser was equal to the dead-state (ambient) temperature. Hence, although the cycle is not very
             efficient, at 24.3%, there is no scope for improving it unless the operating conditions are changed.
                It is possible to evaluate the rational efficiency of a steam plant operating on a Rankine cycle in
             which the condenser temperature is above the ambient temperature. If the dead-state temperature in the
             previous example was taken as 20 C, rather than 81.3 C then the following values would be obtained.


                         b 4 ¼ h 4   T 0 s 4   a 0 ¼ 2799   293   6:340   a 0 ¼ 941:4   a 0 kJ=kg;
                         b 2 ¼ h 2   T 0 s 2   a 0 ¼ 342:1   293   1:091   a 0 ¼ 22:4   a 0 kJ=kg:

                Hence,
                                       b w net ¼ 941:4   22:4 ¼ 919:0kJ=kg:
                Thus, the rational efficiency is

                                          w net   w net  598:2   2:0
                                     R                            ¼ 0:649
                                    h ¼        ¼     ¼
                                         b 4   b 2  b w net  919:0
                This result shows that irreversibilities in the condenser producing a temperature drop of 81.3–20 C

             would reduce the potential efficiency of the power plant significantly. Basically this irreversibility is
             equivalent to a loss of potential work equal to the area of the T–s diagram bounded by the initial dead-
             state temperature of 81.3 C and the final one of 20 C and the entropy difference, as shown in Fig 5.4,


                         Þðs 4   s 2 Þ, which is equal to (354.3   293)   (6.340 – 1.091) ¼ 321.8 kJ/kg.
             i.e. ðT 0 1    T 0 2
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