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Abnormal pore pressure mechanisms  245


              temperature. Hydrocarbon generation is the creation of mobile fluids
              (mainly oil and hydrocarbon gases) from an original solid immobile
              kerogen, causing fluid volume or porosity increase if the fluids cannot be
              expelled. The coincidence of overpressure and hydrocarbon generation was
              given early prominence by the study of the Bakken shale in the Williston
              Basin, Montana and North Dakota, USA (Meissner, 1978a,b). The
              abnormal pressure was attributed by Meissner (1978a) to two processes: (1)
              increased volume of hydrocarbons and residue relative to unaltered organic
              material, and (2) inhibited structural collapse of the rock framework as
              overburden-supporting solid organic matter was converted to hydrocarbon
              pore fluid. He estimated the fluid volume increased at about 25%, with
              even greater increases in volume when maturation proceeded from oil to
              wet gas, and later to dry gas (Fig. 7.8). Spencer (1987) extended the link
              between overpressure and volume increase during oil generation to most of
              the deeper parts of the Rocky Mountain basins. Sweeney et al. (1995)
              modeled volume increases from organic maturation during oil generation,
              leading to 25% of the total overpressure found in the La Luna Formation
              source rocks in the Maracaibo Basin, Venezuela. The distribution of
              hydrocarbon generation with depth indicates that considerable hydrocar-
              bon expulsion and migration occurred in the US Gulf Coast wells at below
              10,000 ft, where vitrinite reflectance values ranged from Ro ¼ 0.65 to
              0.9% through the hydrocarbon generation interval. Results in four wells
              indicate a close relationship between the intervals of high overpressures
              (pressure gradient ranging from 0.76 to 0.86 psi/ft) and the petroleum
              generation and expulsion windows; however, the porosity versus depth plot
              in each well does not show an obvious change (Hunt et al., 1998).
                 The conversion of kerogen to methane from source rocks is the most
              aggressive overpressure mechanism. The rising temperature that accom-
              panies increasing burial depth converts oil in a reservoir into thermal gas. A
              consideration of hydrogen balance shows that approximately one volume of


                                          Wet gas &     Dry gas
                                          condensate           Volume
                                   Oil                         increase



              Figure 7.8 Estimation of volume change when Type II kerogen in the Bakken shale of
              the Williston Basin matures to produce oil, then wet gas and condensate, and finally
              dry gas. (Redrawn from Meissner, 1978b.)
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