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246   Applied Petroleum Geomechanics


                               Pore pressure and stress (MPa)
                         0  20  40  60  80 100 120 140 160 180 200
                       0                                      0
                                              Hydrostatic pressure
                     1000                     Overburden stress  10
                                                              20
                     2000
                                                              30
                     3000
                    Depth (m)  4000                           50


                     5000                        Pp gas generaƟon  60
                                                              40 Time (M.Y.)
                                                              70
                     6000
                                                              80
                     7000
                                                              90
                     8000                                     100
          Figure 7.9 Pore pressure build-up with depth and deposition time showing the pore
          pressure generation trend developed in an isolated system when oil cracks to gas
          (Carcione and Helle, 2002).

          oil thermally cracks to 534.3 volumes of gas at standard temperature and
          pressure during deep burial (Barker, 1990). This extremely high volume
          will develop very high overpressures, if the reservoir is an effectively iso-
          lated system. Fig. 7.9 displays the calculated pore pressure generated from
          oil cracking into gas. It demonstrates clearly the potential for generating
          very high overpressures, most of which are in the geologically unreasonable
          range of greater than the overburden stress.
             Calculations by Barker (1990) show that if the reservoir system remains
          open (i.e., at hydrostatic pressure) and is initially filled with oil that is
          subsequently cracked to gas, then roughly 75% of the gas will be lost or the
          reservoir volume must effectively increase in size, for example, by moving
          the gasewater contact downward. If the reservoir is sealed and totally filled
          with oil, cracking of as little as 1% of the oil is enough to raise pressures to
          1 psi/ft (22.6 MPa/km). When these pressures exceed the fracture gradient,
          the induced fracturing will break the seals, causing gas loss and pressure
          decrease. The induced overpressures from hydrocarbon generation also
          create microfractures in the source rock. Laboratory measurements of
          ultrasonic velocity and anisotropy in kerogen-rich black shales of varying
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