Page 20 - Basic Gas Chromatography
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Introduction   7  Definitions      sepa-  chromatographic   a  effect  thermodynamics)   by  controlled  (parameters  consequence   is   it   ration.   of  more  spends   occurs   B   as   Symbols   and  Terms  Chromatographic   Some   col-   the   leave   of  signal   the   and  symbols,   terms,  chromatographic  codify   to  attempted   has  IUPAC   The   1.3.  Figure   of  recommendations   their   and   [10],  of  chromatography   forms






              a   which   from   A   output   side   chromatographic   kinetic   the   Chapter   to   the   constant   partition   partition   the   stationary   to   stationary   fashion   partition   on   the   into   dominant   the   for   it   solutes   distribution   (partition)   &  Wiley
              as   of   components   right   chromatographic   in   attracted   the   the   relative   the   stationary   comical   adsorption   value   such,   of
              and   B,   The   the   from   equilibrium   the   to   chromatography,   to   of   a   term   passing   is   As   in   absorption   John   Inc.  Sons,
              phase   component   separation   the   shown.   at  shown   individual   the   results   discussed   be   to   an   called   principle   attraction   classified   surface   of   bulk   in   the   use   about   as   processes   numerical   phase.   movement   differences   Contrasts,   &

              mobile   than   Thus,   Eventually   as   an   how   through   which   be   will   component   as   also   in   In   the   be   can   the   on   the   depicted   speak   partitioning   these   a   stationary   the   between   and   Wiley  John


              the   phase.   detector   chromatogram   terms   sometimes   similar   extraction.   greater   into   are   chromatographers   they   of   provides   regulates   summary,   difference   Concepts   of
              in   faster   column.   the   shows   goes   it   broadening,   chromatography,   given   chemical   is   the   attraction   Sorption   sorption   terms   Thus   and   one   present.   the   in   of  the   courtesy
             distribution   column   the   stationary   through   the   through   a   to   rise   figure   the   as  broadens   this   a   of   in   constant,   K,,   constant   liquid-liquid   constant,   the   solute.   and   These   most   process.   phase   Usually   be   can   constant   on   or   and   bed.   In   illustration   Chromatography:   Reproduced




             greater   down   the   in   travel   pass   gives   that   or   of  extent   during   tendency   expressed   distribution   a  controls   the   Alternatively,   the   by   adsorption   absorption.   However,   absorption   stationary   phase.   both   but   distribution   solute   a   of  interaction   chromatographic   Comical   J.   M.,   8.   p.


             a   carried   time   and   detector   Note   widens   work   The   is   distribution   of   sorption   the   stationary   The   by   1.4.   Miller,   1987,
             has    they   umn   exact   phase   The   that   value   called   called   column,   extent
       6          its             at                       1.4.   the   of   tion                            Fig.   From   York,
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