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                                 158.
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                             KcVs

                         Wad
                           (Vr)a
                                 .
                               KcVs
                             +
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                         _
                             Vm
                           Ka
                         Ke
                                                             s
                                                        =
                               =
                             =
                                                             H=
                                 =
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                             Ve
                               Vn
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                                                             13.
                                er
      Terms   41   Theory   Rate   The      Definitions   and  Equations  Chromatographic  Important   Some   3.2  TABLE      [A]s       =  (Ko)a   1.   {Alm   =kB   Ke.   2.   re)  {I   yuo      ~d   (i)   aor   7   Vm   (Wm       From Miller,   1987,   k       =   R)   —   (1   10.   k+1   =a   R)   -   RQ   11.   \o  12.N=  (a) ss (a)   (a)   mJ]  is  acronyms   2d   _   Rs   14.   Wo)s   +   (Wea      were   Plate   B  H=A+=+   (23)   Ci   2+

      and                                  ,   R,.   York,   New   chromatographic   broadening   the   as   nonequilibrium   the   the   Theory.   published   identified   eddy   B-term),   broadening   the   of   Equation
      Concepts                                of  resolution,   Inc.,   Sons,   and  symbols   band   known   the   address   describing   Rate   was   It   [3].   columns;   (the   The   function   Deemter
      Basic                                   Ws   definition   &   Wiley   important   of   be   to   with   deal   not   did   and   approach   the   as   approach   1956   in   packed   in   diffusion   C-term).   a   as   van
                                 /            the   John   Inc.   Sons,   most   the   list   chromatographic   came   not   did   column   known   kinetic   Zuiderweg   (the   H,   the  form,
                                    \/   V   uP               complete          which   it   alternative   the   broadening   molecular   phase   height,
                                 \            illustrating   Contrasts,   and   &   Wiley   of  summary   a   and   explain   model   value,   the   in   an   became   it   Equation   using   and   band   liquid   plate   simple   its
                                            —   peaks  resolved   Concepts   John   of  courtesy   a  contains   equations,   I.  Appendix   THEORY   to  attempts   equilibrium   some   of   was   exist  actually   However,   presented;   Deemter   paper  influential   Klinkenberg,   to  contribute   longitudinal   stationary   the   of   terms   In   u.
                                     /        nearly                              it   that   soon   van   A-term),   the   velocity,
                                       /        Chromatography:   and           an   While   broadening.     in
                                              Two   Reproduced   3.2   in   RATE   earliest   on   was   Original   most   Deemter,   that   (the   in   gas
                                              3.7.   18.    Table   definitions   included   based   Theory.   conditions   factors   effects   transfer   expressed   linear
                                  ,           Fig.   M.,   p.            THE   The     band    The   The   van   sion
      40                                        J.
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