Page 59 - Basic Gas Chromatography

45 in are (27) pub- thin in 31.5%.
kinetics) molecules diameter Small distances depends has [5] columns. i.d. in that transfer only of C-Terms Magnitude 11 18 30 102 Ref. from 5.

Phase Liquid the phase. mobile (slow mixing the because solute the at wall. transfer mass is, term v2 rate the equation radius. Ettre mm 0.32 typical showing 3.3 attributable mass to is it jam) (5.0 Total Cs Relative 48 12.8 26.6 68.5 Taken column.

Silica RIAA PIRI ARONA RRA ARRAN RRRRNARN in transfer mass Inadequate broadening those of ahead the because the for Cy + 6k 11k?) (1+ De k? in C-terms two column the some on given Table in is C-term films thick for Transfer* Mass of Relative Importance (%) Cm 95.2 87.2 73.4 31.5 SE-30 i.d. mm

Fused ERRATIC ERRRRAEIIIISIR ASE MIRA PARADA AR ARRAS RISER RRS Illustration of tube. a through band in move column broadening equation + (1 _ Cu 24 column. the of of the thickness and solutes few a is calculations total the of whereas Types of Importance B k 320 0.56 1.12 160 2.24 80 11.20 16 n-undecane 0.32 on author. the of

Theory PERRI ASIII LLL 3.10. Fig. flow result can the of this minimize small. Golay’s the radius importance relative film the on calculations for his of 95% wm) (Cy), phase, Relative (um) dr 0.25 0.50 1.00 5.00 for data permission with

Rate non-turbulent gas phase center is rc summary (0.25 mobile 3.3 Calculated Reprinted

The the the in columns relatively where The primarily lished A films the TABLE Column A B Cc D *

“OU ‘suog 3 AaTiAA uYyor Jo Asaynos
paonpoiday ‘OzE “d ‘2861 YIOA MON “OUT ‘ SUOS 2 APZTIAA UYOL ‘sisp4gUOD pun sidaqu07 idyd
“DAS OWULOLYD “Wf ‘ITT WL -(0'Z °y) ‘Jaysuez] sseur 0] onp Buluapeolg pueg “6g “BIg

(6)
aseyd Aseuoleys —>
~<— aseyd ajiqow aseyd Asevoners > ~<~ aseyd ajiqow
B}NjOs jo UOIJe1]UaDU0D aINjOs yO UONeUaDU0D